Benzoxazine-functionalized multi-walled carbon nanotubes for preparation of electrically-conductive polybenzoxazines
作者： Yie-Hsiang Wang , Chia-Ming Chang , Ying-Ling Liu
DOI: 10.1016/J.POLYMER.2011.11.040
关键词:
摘要: Abstract Functionalization of multi-walled carbon nanotubes (MWCNTs) has been carried out using benzoxazine-containing compound (BPA-FBz) and polymer (PFBz) as modifiers through Diels–Alder reaction. The benzoxazine-functionalized MWCNTs (MWCNT-FBz MWCNT-PFBz) have characterized with Raman spectroscopy, X-ray photoelectron thermogravimetric analyzer, high-resolution transmission electron microscopy. MWCNT-FBz MWCNT-PFBz are thermally cross-linkable nanomaterials could be fabricated press molding other thermal-forming processes. cross-linked pellets show surface electrical conductivities 0.05 S cm−1. Moreover, nanocomposites also prepared from BPA-FBz MWCNT-FBz. shown high (about 7 × 10−5 S cm−1) good mechanical strength. attractive properties attributed to the compatibility between polybenzoxazine matrix MWCNT-FBz, benzoxazine groups copolymerize in preparation nanocomposites.
elsevier.com
sci-hub.se 参考文章(45)
Hatsuo Ishida, Daniel P. Sanders, Regioselectivity and network structure of difunctional alkyl-substituted aromatic amine-based polybenzoxazines Macromolecules. ,vol. 33, pp. 8149- 8157 ,(2000) , 10.1021/MA991836T
Ying-Ling Liu, Che-Yuan Chang, Chih-Yuan Hsu, Min-Chi Tseng, Ching-I Chou, Preparation, characterization, and properties of fluorene-containing benzoxazine and its corresponding cross-linked polymer Journal of Polymer Science Part A: Polymer Chemistry. ,vol. 48, pp. 4020- 4026 ,(2010) , 10.1002/POLA.24187
Baris Kiskan, Burcin Gacal, M. Atilla Tasdelen, Demet Colak, Yusuf Yagci, Design and synthesis of thermally curable polymers with benzoxazine functionalities Macromolecular Symposia. ,vol. 245, pp. 27- 33 ,(2006) , 10.1002/MASY.200651305
Baris Kiskan, A. Levent Demirel, Orhan Kamer, Yusuf Yagci, Synthesis and characterization of nanomagnetite thermosets based on benzoxazines Journal of Polymer Science Part A. ,vol. 46, pp. 6780- 6788 ,(2008) , 10.1002/POLA.23023
Yuan-Jyh Lee, Shiao-Wei Kuo, Yi-Che Su, Jem-Kun Chen, Cheng-Wei Tu, Feng-Chih Chang, Syntheses, thermal properties, and phase morphologies of novel benzoxazines functionalized with polyhedral oligomeric silsesquioxane (POSS) nanocomposites Polymer. ,vol. 45, pp. 6321- 6331 ,(2004) , 10.1016/J.POLYMER.2004.04.055
Ryoichi Kudoh, Atsushi Sudo, Takeshi Endo, A Highly Reactive Benzoxazine Monomer, 1-(2-Hydroxyethyl)-1,3-Benzoxazine: Activation of Benzoxazine by Neighboring Group Participation of Hydroxyl Group Macromolecules. ,vol. 43, pp. 1185- 1187 ,(2010) , 10.1021/MA902416H
Yi Lin, Bing Zhou, K. A. Shiral Fernando, Ping Liu, Lawrence F. Allard, Ya-Ping Sun, Polymeric Carbon Nanocomposites from Carbon Nanotubes Functionalized with Matrix Polymer Macromolecules. ,vol. 36, pp. 7199- 7204 ,(2003) , 10.1021/MA0348876
Tianle Zhou, Xin Wang, Tianchi Wang, Cure reaction of multi‐walled carbon nanotubes/diglycidyl ether of bisphenol A/2‐ethyl‐4‐methylimidazole (MWCNTs/DGEBA/EMI‐2,4) nanocomposites: effect of carboxylic functionalization of MWCNTs Polymer International. ,vol. 58, pp. 445- 452 ,(2009) , 10.1002/PI.2558
Ying-Ling Liu, Ching-I Chou, High performance benzoxazine monomers and polymers containing furan groups Journal of Polymer Science Part A: Polymer Chemistry. ,vol. 43, pp. 5267- 5282 ,(2005) , 10.1002/POLA.21023
Ying-Ling Liu, Yu-Huei Su, Chia-Ming Chang, Suryani, Da-Ming Wang, Juin-Yih Lai, Preparation and applications of Nafion-functionalized multiwalled carbon nanotubes for proton exchange membrane fuel cells Journal of Materials Chemistry. ,vol. 20, pp. 4409- 4416 ,(2010) , 10.1039/C000099J