Electrochemical and XPS investigation of the corrosion behavior of Alloy 690 at high-temperature water

作者: Zhengang Duan , Farzin Arjmand , Lefu Zhang , Fanjiang Meng , Hiroaki ABE

DOI: 10.1007/S10008-015-2856-1

关键词:

摘要: The effects of solution temperature, pH, and dissolved oxygen concentration on the electrochemical behavior Alloy 690 in high-temperature water were investigated by potentiodynamic polarization, oxide films developed specimens characterized X-ray photoelectron spectroscopy (XPS). results revealed that deaerated + ETA decreasing temperature pH environment improves passivity film 690. XPS analysis formed after exposing to showed outer layer consists Ni hydroxides, Cr NiFe2O4, while Cr2O3 (Ni x , Fe1 − x ) Cr2O4 form major part inner film.

参考文章(31)
Damien Féron, Nuclear corrosion science and engineering Woodhead Publishing Limited. ,(2012) , 10.1533/9780857095343
Myung Ji Seo, Hee-Sang Shim, Kyung Mo Kim, Sun-Ig Hong, Do Haeng Hur, Influence of surface roughness on the corrosion behavior of Alloy 690TT in PWR primary water Nuclear Engineering and Design. ,vol. 280, pp. 62- 68 ,(2014) , 10.1016/J.NUCENGDES.2014.08.023
Zhiming Zhang, Jianqiu Wang, En-Hou Han, Wei Ke, Influence of dissolved oxygen on oxide films of Alloy 690TT with different surface status in simulated primary water Corrosion Science. ,vol. 53, pp. 3623- 3635 ,(2011) , 10.1016/J.CORSCI.2011.07.012
D. L. Harrod, R. E. Gold, R. J. Jacko, Alloy optimization for PWR steam generator heat-transfer tubing JOM. ,vol. 53, pp. 14- 17 ,(2001) , 10.1007/S11837-001-0080-1
J. Robertson, The mechanism of high temperature aqueous corrosion of steel Corrosion Science. ,vol. 29, pp. 1275- 1291 ,(1989) , 10.1016/0010-938X(89)90120-0
Geogy J Abraham, Rajan Bhambroo, V Kain, R Shekhar, GK Dey, VS Raja, None, Electrochemical characterization of oxide film formed at high temperature on Alloy 690 Nuclear Engineering and Design. ,vol. 243, pp. 69- 75 ,(2012) , 10.1016/J.NUCENGDES.2011.11.018
N. S. McIntyre, M. G. Cook, X-ray photoelectron studies on some oxides and hydroxides of cobalt, nickel, and copper Analytical Chemistry. ,vol. 47, pp. 2208- 2213 ,(1975) , 10.1021/AC60363A034
Stephen E. Ziemniak, Michael Hanson, Corrosion behavior of NiCrFe Alloy 600 in high temperature, hydrogenated water Corrosion Science. ,vol. 48, pp. 498- 521 ,(2006) , 10.1016/J.CORSCI.2005.01.006