Kinetics of the copolymerization of alkylene oxides with glycidyl methacrylate
作者： Gulnare Ahmetli , Ahmet Kocak , Zafer Yazicigil
DOI: 10.1002/APP.27069
关键词:
摘要: In the present study, kinetics of copolymerization reaction propylene oxide (PO) and butylene (BO) with glycidyl methacrylate (GMA) in presence BF3·O(C2H5)2 catalyst were investigated. The kinetic parameters activation energy calculated. amounts reacting PO, BO, GMA during determined by chromatographic method, because same conditions carried out for them. It was that rate PO (r0) BO higher than GMA, but (E) BO. reaction, constant, calculated from amount copolymer obtained respect to time. structures synthesized copolymers spectral chemical analysis methods. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci
sci-hub.se 参考文章(10)
Su Chen, Ping Zhang, Li Chen, Fe/Zn double metal cyanide (DMC) catalyzed ring-opening polymerization of propylene oxide: Part 3. Synthesis of DMC catalysts Progress in Organic Coatings. ,vol. 50, pp. 269- 272 ,(2004) , 10.1016/J.PORGCOAT.2004.03.003
G.N. Komratov, R.A. Barzykina, G.V. Korovina, Effect of polar compounds on copolymerization of propylene oxide and tetrahydrofuran Polymer Science U.s.s.r.. ,vol. 22, pp. 2571- 2577 ,(1980) , 10.1016/0032-3950(80)90165-3
Yasukatsu Maeda, Atsuyoshi Nakayama, Norioki Kawasaki, Kazuko Hayashi, Seiichi Aiba, Noboru Yamamoto, Ring-opening copolymerization of succinic anhydride with ethylene oxide initiated by magnesium diethoxide Polymer. ,vol. 38, pp. 4719- 4725 ,(1997) , 10.1016/S0032-3861(96)01088-9
Alice Rolland, Damien Hérault, François Touchard, Christine Saluzzo, Raphaël Duval, Marc Lemaire, Enantiopure poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate): a new material for supported catalytic asymmetric hydrogen transfer reduction Tetrahedron-asymmetry. ,vol. 12, pp. 811- 815 ,(2001) , 10.1016/S0957-4166(01)00129-X
J. Gole, G. Merle, J.P. Pascault, Graphite intercalation compounds as anionic polymerization initiators Synthetic Metals. ,vol. 4, pp. 269- 297 ,(1982) , 10.1016/0379-6779(82)90001-7
M.F. Sorokin, M.M. Babkina, Copolymerization kinetics of butyl- and glycidyl methacrylate with methacrylic acid Polymer Science U.s.s.r.. ,vol. 9, pp. 1012- 1018 ,(1967) , 10.1016/0032-3950(67)90301-2
I.M. Kochnov, M.F. Sorokin, Kinetics of the copolymerization of glycidyl methacrylate and styrene Polymer Science U.S.S.R.. ,vol. 7, pp. 2100- 2108 ,(1965) , 10.1016/0032-3950(65)90496-X
G. Ahmetli, A. Kocak, N. Sen, R. Kurbanli, Adhesion and corrosion resistance properties of coatings obtained from modified low-molecular-weight polystyrenes Journal of Adhesion Science and Technology. ,vol. 20, pp. 1431- 1441 ,(2006) , 10.1163/156856106778666453
A.Kh. Bulai, I.Ya. Slonim, D.Ya. Filippenko, N.V. Khrenova, Synthesis of unsaturated polyesters from maleic anhydride and isobutylene oxide Polymer Science U.S.S.R.. ,vol. 30, pp. 1874- 1879 ,(1988) , 10.1016/0032-3950(88)90419-4
Valérie Langlois, Karine Vallee-Rehel, Jean Jacques Peron, Alain le Borgne, Michael Walls, Philippe Guerin, Synthesis and hydrolytic degradation of graft copolymers containing poly(lactic acid) side chains Polymer Degradation and Stability. ,vol. 76, pp. 411- 417 ,(2002) , 10.1016/S0141-3910(02)00042-3