A Highly Active and Recyclable Catalyst: Phosphine Dendrimer‐Stabilized Nickel Nanoparticles for the Suzuki Coupling Reaction
作者： Lei Wu , Jie Ling , Zong-Quan Wu
关键词:
摘要: We report here the first dendritic phosphine-stabilized nickel nanoparticles, which can be prepared from nickel(II) chloride, a third generation phosphine dendrimer and surfactant tetraoctylammonium bromide (TOABr) by two-phase reduction using sodium borohydride. The resulting nanoparticles are found to highly active recyclable catalyst for Suzuki coupling reactions, especially those extended aryl chloride substrates, affording biaryls in moderate good yields.
sci-hub.se 参考文章(53)
Valentine P. Ananikov, Konstantin A. Gayduk, Irina P. Beletskaya, Victor N. Khrustalev, Mikhail Yu. Antipin, Remarkable Ligand Effect in Ni- and Pd-Catalyzed Bisthiolation and Bisselenation of Terminal Alkynes: Solving the Problem of Stereoselective Dialkyldichalcogenide Addition to the CC Bond Chemistry: A European Journal. ,vol. 14, pp. 2420- 2434 ,(2008) , 10.1002/CHEM.200701278
Mathias Brust, Merryl Walker, Donald Bethell, David J. Schiffrin, Robin Whyman, Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system Journal of The Chemical Society, Chemical Communications. pp. 801- 802 ,(1994) , 10.1039/C39940000801
Attilio Siani, Oleg S. Alexeev, D. Samuel Deutsch, John R. Monnier, Paul T. Fanson, Hirohito Hirata, Shinichi Matsumoto, Christopher T. Williams, Michael D. Amiridis, Dendrimer-mediated synthesis of subnanometer-sized Rh particles supported on ZrO2 Journal of Catalysis. ,vol. 266, pp. 331- 342 ,(2009) , 10.1016/J.JCAT.2009.06.025
Didier Astruc, Palladium catalysis using dendrimers: molecular catalysts versus nanoparticles Tetrahedron-asymmetry. ,vol. 21, pp. 1041- 1054 ,(2010) , 10.1016/J.TETASY.2010.04.062
Mostafa A. El-Sayed, Some interesting properties of metals confined in time and nanometer space of different shapes. Accounts of Chemical Research. ,vol. 34, pp. 257- 264 ,(2001) , 10.1021/AR960016N
A. T. Bell, The impact of nanoscience on heterogeneous catalysis Science. ,vol. 299, pp. 1688- 1691 ,(2003) , 10.1126/SCIENCE.1083671
Wenyu Huang, John N. Kuhn, Chia-Kuang Tsung, Yawen Zhang, Susan E. Habas, Peidong Yang, Gabor A. Somorjai, Dendrimer Templated Synthesis of One Nanometer Rh and Pt Particles Supported on Mesoporous Silica: Catalytic Activity for Ethylene and Pyrrole Hydrogenation Nano Letters. ,vol. 8, pp. 2027- 2034 ,(2008) , 10.1021/NL801325M
Kunio Esumi, Ryoko Isono, Tomokazu Yoshimura, Preparation of PAMAM− and PPI−Metal (Silver, Platinum, and Palladium) Nanocomposites and Their Catalytic Activities for Reduction of 4-Nitrophenol Langmuir. ,vol. 20, pp. 237- 243 ,(2004) , 10.1021/LA035440T
Kiyofumi Inamoto, Jun-ichi Kuroda, Kou Hiroya, Yukio Noda, Masashi Watanabe, Takao Sakamoto, Synthesis and Catalytic Activity of a Pincer-Type Bis(imidazolin-2-ylidene) Nickel(II) Complex Organometallics. ,vol. 25, pp. 3095- 3098 ,(2006) , 10.1021/OM060043+
Steven R. Isaacs, Erin C. Cutler, Joon-Seo Park, T. Randall Lee, Young-Seok Shon, Synthesis of Tetraoctylammonium-Protected Gold Nanoparticles with Improved Stability Langmuir. ,vol. 21, pp. 5689- 5692 ,(2005) , 10.1021/LA050656B