High-Temperature Interactions between Coal Char and Mixtures of Calcium Oxide, Quartz, and Kaolinite

作者: Jie Wang , Kayoko Morishita , Takayuki Takarada

DOI: 10.1021/EF0100092

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摘要: The interaction between coal char and mixtures of calcium oxide, quartz, meta-kaolinite were investigated by heating to 1600 °C under Ar. Calcium oxide was gradually reduced in the temperature range 950−1450 °C, then rapidly carbided above 1450 releasing CO. In case CaSiO3, carbothermal reduction SiO2 component started at 1200 preference CaO component, forming SiC Ca2SiO4; higher temperature, both components Ca2SiO4 significantly. When mixed with meta-kaolinite, two phases reacted each other below °C. chemically bound CaO−SiO2−Al2O3 system, reactivity sequence > Al2O3; also began SiC; upon presence a alumimum carbide (approximately CaAl1.9O4C0.4) notable. became difficult reduce as it combined Al2O3. On o...

参考文章(19)
Jie Wang, Takayuki Takarada, Fixation of lead chloride on kaolinite and bentonite at temperatures between 550 and 950 °C Industrial & Engineering Chemistry Research. ,vol. 39, pp. 335- 341 ,(2000) , 10.1021/IE9905097
Jie Wang, Risa Ishida, Takayuki Takarada, Carbothermal Reactions of Quartz and Kaolinite with Coal Char Energy & Fuels. ,vol. 14, pp. 1108- 1114 ,(2000) , 10.1021/EF000084X
Hiroaki Tagawa, Hideo Sugawara, The Kinetics of the Formation of Calcium Carbide in a Solid-Solid Reaction Bulletin of the Chemical Society of Japan. ,vol. 35, pp. 1276- 1279 ,(1962) , 10.1246/BCSJ.35.1276
Ljubis̆a R. Radović, Philip L. Walker, Robert G. Jenkins, Effect of lignite pyrolysis conditions on calcium oxide dispersion and subsequent char reactivity Fuel. ,vol. 62, pp. 209- 212 ,(1983) , 10.1016/0016-2361(83)90200-4
Yasuo Ohtsuka, Akira Tomita, Calcium catalysed steam gasification of Yallourn brown coal Fuel. ,vol. 65, pp. 1653- 1657 ,(1986) , 10.1016/0016-2361(86)90264-4
A OYA, T FUKATSU, S OTANI, H MARSH, Catalytic graphitization of cokes by indigeneous mineral matter Fuel. ,vol. 62, pp. 502- 507 ,(1983) , 10.1016/0016-2361(83)90217-X
S. Y. Lin, M. Hirato, M. Horio, The characteristics of coal char gasification at around ash melting temperature Energy & Fuels. ,vol. 8, pp. 598- 606 ,(1994) , 10.1021/EF00045A014
Jeffrey C. Nankervis, Robert B. Furlong, Phase changes in mineral matter of North Dakota lignites caused by heating to 1200 °C Fuel. ,vol. 59, pp. 425- 430 ,(1980) , 10.1016/0016-2361(80)90196-9
D. Cazorla-Amoros, A. Linares-Solano, C. Salinas-Martinez de Lecea, J. P. Joly, A temperature-programmed reaction study of calcium-catalyzed carbon gasification Energy & Fuels. ,vol. 6, pp. 287- 293 ,(1992) , 10.1021/EF00033A008