Ostwald ripening in emulsions
作者： A.S Kabalnov , K.N Makarov , A.V Pertzov , E.D Shchukin
DOI: 10.1016/0021-9797(90)90184-P
关键词:
摘要: Abstract Kinetics of Ostwald ripening in emulsions aliphatic C9C16 hydrocarbons stabilized by sodium dodecyl sulfate (SDS) was studied means photon correlation spectroscopy. Two kinds systems were studied. In the first case, emulsion medium a diluted molecular solution SDS; second one, concentrated micellar SDS. The experimental values absolute rates compared with theoretical values. It found that are systematically higher factor ∼2.5 than ones. shown solubility did not contribute essentially to kinetics investigated systems. A method for evaluation organic liquids water, very low detection limit about ∼10−11 ml/ml, proposed.
harvard.edu
elsevier.com
sci-hub.se 参考文章(21)
Milton J. Rosen, Surfactants and Interfacial Phenomena ,(1978)
A.S. Kabalnov, A.V. Pertzov, E.D. Shchukin, Ostwald ripening in emulsions Journal of Colloid and Interface Science. ,vol. 118, pp. 590- 597 ,(1987) , 10.1016/0021-9797(87)90492-9
S.S Davis, H.P Round, T.S Purewal, Ostwald ripening and the stability of emulsion systems: an explanation for the effect of an added third component Journal of Colloid and Interface Science. ,vol. 80, pp. 508- 511 ,(1981) , 10.1016/0021-9797(81)90210-1
C. McAuliffe, Solubility in Water of Normal C9 and C10, Alkane Hydrocarbons Science. ,vol. 163, pp. 478- 479 ,(1969) , 10.1126/SCIENCE.163.3866.478
Milton Kerker, A.Lucile Cox, Melvin D Shoenberg, Maximum particle sizes in polydispersed aerosols Journal of Colloid Science. ,vol. 10, pp. 413- 427 ,(1955) , 10.1016/0095-8522(55)90059-3
Keith P. Anderson, Richard L. Snow, A relative deviation, least squares method of data treatment Journal of Chemical Education. ,vol. 44, pp. 756- ,(1967) , 10.1021/ED044P756
W.I. Higuchi, Jagdish Misra, Physical Degradation of Emulsions Via the Molecular Diffusion Route and the Possible Prevention Thereof Journal of Pharmaceutical Sciences. ,vol. 51, pp. 459- 466 ,(1962) , 10.1002/JPS.2600510514
I.M. Lifshitz, V.V. Slyozov, The kinetics of precipitation from supersaturated solid solutions Journal of Physics and Chemistry of Solids. ,vol. 19, pp. 35- 50 ,(1961) , 10.1016/0022-3697(61)90054-3
Jack Hine, Pradip K. Mookerjee, Structural effects on rates and equilibriums. XIX. Intrinsic hydrophilic character of organic compounds. Correlations in terms of structural contributions Journal of Organic Chemistry. ,vol. 40, pp. 292- 298 ,(1975) , 10.1021/JO00891A006
P. W. Voorhees, The Theory of Ostwald Ripening Journal of Statistical Physics. ,vol. 38, pp. 231- 252 ,(1985) , 10.1007/BF01017860