New Developments in the Cyclopentadienyl Chemistry of the Alkaline-Earth Metals
DOI: 10.1021/OM020168O
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摘要: Recent developments in the chemistry of cyclopentadienyl derivatives alkaline-earth (group 2) metals are reviewed. New complexes and their applications organometallic materials synthesis reflect growing number ways that can be used to manipulate alkaline-earth−cyclopentadienyl bond. Complementing experimental work computational studies using density functional theory methods. These now reproduce geometries many group 2 molecules with encouraging accuracy have provided new insight into energetics metal−ring bonding. The progress made past decade indicates more expansion expected.
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