(K, Na)NbO3-based lead-free piezoceramics: Phase transition, sintering and property enhancement

作者: Ke Wang , Jing-Feng Li

DOI: 10.1007/S40145-012-0003-3

关键词:

摘要: Most widely used piezoelectric ceramics are based on Pb(Zr,Ti)O3 (PZT) composition which has adverse environmental and health effects due to its high lead content. Environmental safety concerns with respect the utilization, recycling, disposal of lead-based have induced a new surge in developing lead-free ceramics. Among all ceramics, (K,Na)NbO3 (KNN) drawn increasing attention because well-balanced properties better compatibility. On basis author's work, this review summarizes progress that been made recent years development KNN-based including crystallographic structure phase transition analysis, pressurized solid-state sintering as well liquid-phase-assisted process, poling treatment for property enhancement. All all, KNN is promising system, but more research still required both from academic industrial interests.

参考文章(108)
Pei Zhao, Bo-Ping Zhang, High Piezoelectric d33 Coefficient in Li/Ta/Sb-Codoped Lead-Free (Na,K)NbO3 Ceramics Sintered at Optimal Temperature Journal of the American Ceramic Society. ,vol. 91, pp. 3078- 3081 ,(2008) , 10.1111/J.1551-2916.2008.02518.X
Jia-Jun Zhou, Jing-Feng Li, Ke Wang, Xiao-Wen Zhang, Phase structure and electrical properties of (Li,Ta)-doped (K,Na)NbO3 lead-free piezoceramics in the vicinity of Na/K = 50/50 Journal of Materials Science. ,vol. 46, pp. 5111- 5116 ,(2011) , 10.1007/S10853-011-5442-7
Mingsen Guo, K. H. Lam, D. M. Lin, S. Wang, K. W. Kwok, Helen L. W. Chan, X. Z. Zhao, A Rosen-type piezoelectric transformer employing lead-free K0.5Na0.5NbO3 ceramics Journal of Materials Science. ,vol. 43, pp. 709- 714 ,(2008) , 10.1007/S10853-007-2199-0
Ruzhong Zuo, Zhengkui Xu, Longtu Li, Dielectric and piezoelectric properties of Fe2O3-doped (Na0.5K0.5)0.96Li0.04Nb0.86Ta0.1Sb0.04O3 lead-free ceramics Journal of Physics and Chemistry of Solids. ,vol. 69, pp. 1728- 1732 ,(2008) , 10.1016/J.JPCS.2008.01.003
Yasuyoshi Saito, Hisaaki Takao, Toshihiko Tani, Tatsuhiko Nonoyama, Kazumasa Takatori, Takahiko Homma, Toshiatsu Nagaya, Masaya Nakamura, Lead-free piezoceramics Nature. ,vol. 432, pp. 84- 87 ,(2004) , 10.1038/NATURE03028
F. Rubio-Marcos, P. Ochoa, J.F. Fernandez, Sintering and properties of lead-free (K,Na,Li)(Nb,Ta,Sb)O3 ceramics Journal of The European Ceramic Society. ,vol. 27, pp. 4125- 4129 ,(2007) , 10.1016/J.JEURCERAMSOC.2007.02.110
D Damjanovic, Martin H H Kuball, N Setter, N Klein, HJ Trodahl, D Rytz, B Ludbrook, Raman spectroscopy of (K,Na)NbO3 and (K,Na)1−xLixNbO3 Applied Physics Letters. ,vol. 93, pp. 262901- 262901 ,(2008) , 10.1063/1.3056658
Masato Matsubara, Toshiaki Yamaguchi, Koichi Kikuta, Shin-ichi Hirano, Effect of Li Substitution on the Piezoelectric Properties of Potassium Sodium Niobate Ceramics Japanese Journal of Applied Physics. ,vol. 44, pp. 6136- 6142 ,(2005) , 10.1143/JJAP.44.6136
Dunmin Lin, K. W. Kwok, H. L. W. Chan, Microstructure, phase transition, and electrical properties of (K0.5Na0.5)1−xLix(Nb1−yTay)O3 lead-free piezoelectric ceramics Journal of Applied Physics. ,vol. 102, pp. 034102- ,(2007) , 10.1063/1.2761852