Expedient synthesis of highly substituted pyrroles via tandem rearrangement of α-diazo oxime ethers
作者： Yaojia Jiang , Wei Chuen Chan , Cheol-Min Park
DOI: 10.1021/JA300552C
关键词:
摘要: An efficient rhodium-catalyzed synthesis of 2H-azirines and pyrroles has been developed. Novel rearrangement α-oximino ketenes derived from α-diazo oxime ethers provides bearing quaternary centers allows for subsequent to highly substituted in excellent yields.
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