Study of the Interface between Polyacrylonitrile Thin Films and a Nickel Cathode: Ni 3d States Analysed by EXES

作者: Philippe Jonnard , Fran�oise Vergand , Pierre-Fran�ois Staub , Christiane Bonnelle , Guy Deniau

DOI: 10.1002/(SICI)1096-9918(199605)24:5<339::AID-SIA124>3.0.CO;2-Y

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摘要: The interaction between a nickel substrate and thin polyacrylonitrile films is studied by electron-induced x-ray emission spectroscopy (EXES). analysis of the metal 3d distribution at interface suggests that direct takes place metallic sites monomer molecules when cathodically polarized. existence bonds due to mixing Ni C 2p states shown. In contrast, there no detectable in absence polarization surface.

参考文章(21)
Gerard Tourillon, Pierre-Camille Lacaze, Jacques-Emile Dubois, Electrochemical formation of thin polyacetonitrile films on a Pt surface Journal of Electroanalytical Chemistry. ,vol. 100, pp. 247- 262 ,(1979) , 10.1016/S0022-0728(79)80166-7
L. Papagno, M. Conti, L. S. Caputi, J. Anderson, G. J. Lapeyre, Angle-resolved photoemission investigation of the (2 x 1) carbidic carbon on Ni(110). Physical Review B. ,vol. 44, pp. 1904- 1909 ,(1991) , 10.1103/PHYSREVB.44.1904
Guy Deniau, Gérard Lécayon, Pascal Viel, Gilbert Zalczer, Claude Boiziau, Geneviève Hennico, Joseph Delhalle, Polymer-film formation on the surface of a cathodically polarized nickel electrode in the presence of 4-chlorostyrene Journal of The Chemical Society-perkin Transactions 1. pp. 1433- 1443 ,(1990) , 10.1039/P29900001433
G. Lecayon, Y. Bouizem, C. Le Gressus, C. Reynaud, C. Boiziau, C. Juret, Grafting and growing mechanisms of polymerised organic films onto metallic surfaces Chemical Physics Letters. ,vol. 91, pp. 506- 510 ,(1982) , 10.1016/0009-2614(82)83100-X
M Kefi, P Jonnard, F Vergand, A Amamou, C Bonnelle, Electron energy distributions at AuPd/alumina interfaces Journal of Physics D. ,vol. 27, pp. 1952- 1958 ,(1994) , 10.1088/0022-3727/27/9/021
Frank Szmulowicz, Douglas M. Pease, Augmented-plane-wave calculation and measurements ofKandLx-ray spectra for solid Ni Physical Review B. ,vol. 17, pp. 3341- 3355 ,(1978) , 10.1103/PHYSREVB.17.3341
C. Bonnelle, F. Vergand, P. Jonnard, J.‐M. André, P. F. Staub, P. Avila, P. Chargelègue, M.‐F. Fontaine, D. Laporte, P. Paquier, A. Ringuenet, B. Rodriguez, Instrument for research on interfaces and surfaces Review of Scientific Instruments. ,vol. 65, pp. 3466- 3471 ,(1994) , 10.1063/1.1144524
Gérard Tourillon, Richard Garrett, Nancy Lazarz, Michèle Raynaud, Cécile Reynaud, Gérard Lécayon, Pascal Viel, A NEXAFS Study of Thin Polyacrylonitrile Films Electrochemically Deposited on Ni: The Effect of the Film Thickness and Annealing Treatment Journal of The Electrochemical Society. ,vol. 137, pp. 2499- 2501 ,(1990) , 10.1149/1.2086975