Benzothiadiazole functionalized Co-doped MIL-53-NH2 with electron deficient units for enhanced photocatalytic degradation of bisphenol A and ofloxacin under visible light.

作者: Shi-Wen Lv , Jing-Min Liu , Ning Zhao , Chun-Yang Li , Zhi-Hao Wang

DOI: 10.1016/J.JHAZMAT.2019.122011

关键词:

摘要: Nowadays, designing highly active photocatalysts for pollutant degradation under visible light still remains a challenging problem. Herein, a novel benzothiadiazole functionalized Co-doped MOF-based photocatalyst with electron deficient unit was first synthesized via a feasible step-by-step assembly strategy. Benzothiadiazole, as typical electron deficient group, could effectively promote the separation and transfer of photoinduced charge carriers. The implantation of Co ion could be served as an effective mediator to further …

参考文章(42)
Jaromir Michałowicz, Bisphenol A--sources, toxicity and biotransformation. Environmental Toxicology and Pharmacology. ,vol. 37, pp. 738- 758 ,(2014) , 10.1016/J.ETAP.2014.02.003
Zubair Hasan, Minman Tong, Beom K. Jung, Imteaz Ahmed, Chongli Zhong, Sung Hwa Jhung, Adsorption of Pyridine over Amino-Functionalized Metal–Organic Frameworks: Attraction via Hydrogen Bonding versus Base–Base Repulsion Journal of Physical Chemistry C. ,vol. 118, pp. 21049- 21056 ,(2014) , 10.1021/JP507074X
Hasmukh A. Patel, Sang Hyun Je, Joonho Park, Dennis P. Chen, Yousung Jung, Cafer T. Yavuz, Ali Coskun, Unprecedented high-temperature CO 2 selectivity in N 2 -phobic nanoporous covalent organic polymers Nature Communications. ,vol. 4, pp. 1357- ,(2013) , 10.1038/NCOMMS2359
Hongying Zhao, Lin Qian, Huanli Lv, Yanbin Wang, Guohua Zhao, Introduction of a Fe3O4 Core Enhances the Photocatalytic Activity of MIL‐100(Fe) with Tunable Shell Thickness in the Presence of H2O2 Chemcatchem. ,vol. 7, pp. 4148- 4155 ,(2015) , 10.1002/CCTC.201500801
Dengrong Sun, Wenjun Liu, Mei Qiu, Yongfan Zhang, Zhaohui Li, Introduction of a mediator for enhancing photocatalytic performance via post-synthetic metal exchange in metal–organic frameworks (MOFs) Chemical Communications. ,vol. 51, pp. 2056- 2059 ,(2015) , 10.1039/C4CC09407G
Xiaobo Wang, Yanlei Qin, Lihua Zhu, Heqing Tang, Nitrogen-Doped Reduced Graphene Oxide as a Bifunctional Material for Removing Bisphenols: Synergistic Effect between Adsorption and Catalysis. Environmental Science & Technology. ,vol. 49, pp. 6855- 6864 ,(2015) , 10.1021/ACS.EST.5B01059
Syam S. Andra, Christine Austin, Juan Yang, Dhavalkumar Patel, Manish Arora, Recent advances in simultaneous analysis of bisphenol A and its conjugates in human matrices: Exposure biomarker perspectives. Science of The Total Environment. ,vol. 572, pp. 770- 781 ,(2016) , 10.1016/J.SCITOTENV.2016.07.062
Jian-Ping Zou, Dan-Dan Wu, Jinming Luo, Qiu-Ju Xing, Xu-Biao Luo, Wen-Hua Dong, Sheng-Lian Luo, Hong-Mei Du, Steven L. Suib, A Strategy for One-Pot Conversion of Organic Pollutants into Useful Hydrocarbons through Coupling Photodegradation of MB with Photoreduction of CO2 ACS Catalysis. ,vol. 6, pp. 6861- 6867 ,(2016) , 10.1021/ACSCATAL.6B01729
Xianghui Li, Weilin Guo, Zhonghua Liu, Ruiqin Wang, Hua Liu, Quinone-modified NH2-MIL-101(Fe) composite as a redox mediator for improved degradation of bisphenol A. Journal of Hazardous Materials. ,vol. 324, pp. 665- 672 ,(2017) , 10.1016/J.JHAZMAT.2016.11.040