Formic acid/acetone-organosolv pulping of white-rotted Pinus radiata softwood.

作者: Andr� Ferraz , Jaime Rodr�guez , Juanita Freer , Jaime Baeza

DOI: 10.1002/1097-4660(200012)75:12<1190::AID-JCTB342>3.0.CO;2-K

关键词:

摘要: Organosolv pulping of fungally pretreated samples Pinus radiata was evaluated. A screening study using five white-rot fungi indicated that Ceriporiopsis subvermisopora and Punctularia artropurpurascens were the most selective ones for lignin degradation. These further cultured in bioreactors containing 2.5 kg wood chips. Fungally-pretreated delignified by formic acid/acetone (7:3) at 150°C. Pulping kinetics strength properties resulting unbleached pulps Delignification rates xylan solubilization higher decayed than undecayed control, except sample biotreated with P. 30 days. C. subvermispora proved appropriate treating before organosolv pulping, since pretreatment this fungus resulted faster delignification lower residual lignin. Increases tensile index ranging from 3% to 22% observed prepared samples, independently both fungal species used extent biodegradation expressed as weight loss. However, tear burst indexes brightness or similar those control.

参考文章(14)
Christopher J. Biermann, Essentials of Pulping and Papermaking ,(1993)
Thomas Joseph McDonough, The chemistry of organosolv delignification Tappi Journal. ,vol. 76, pp. 186- 193 ,(1993)
G. Vázquez, G. Antorrena, J. González, Kinetics of polysaccharide hydrolysis in the acid-catalysed delignification of eucalyptus globulus wood by acetic acid Wood Science and Technology. ,vol. 30, pp. 31- 38 ,(1995) , 10.1007/BF00195266
Raymond A. Young, Comparison of the properties of chemical cellulose pulps Cellulose. ,vol. 1, pp. 107- 130 ,(1994) , 10.1007/BF00819662
T. Higuchi, Lignin biochemistry: Biosynthesis and biodegradation * Wood Science and Technology. ,vol. 24, pp. 23- 63 ,(1990) , 10.1007/BF00225306
J.C. Parajó, J.L. Alonso, D. Vázquez, V. Santos, Optimization of Catalysed Acetosolv Fractionation of Pine Wood Holzforschung. ,vol. 47, pp. 188- 196 ,(1993) , 10.1515/HFSG.1993.47.3.188
André Ferraz, Jaime Baeza, Jaime Rodriguez, Juanita Freer, Estimating the chemical composition of biodegraded pine and eucalyptus wood by DRIFT spectroscopy and multivariate analysis Bioresource Technology. ,vol. 74, pp. 201- 212 ,(2000) , 10.1016/S0960-8524(00)00024-9
André Ferraz, Régis Mendonça, Flávio T da Silva, None, Organosolv delignification of white- and brown-rotted Eucalyptus grandis hardwood. Journal of Chemical Technology & Biotechnology. ,vol. 75, pp. 18- 24 ,(2000) , 10.1002/(SICI)1097-4660(200001)75:1<18::AID-JCTB169>3.0.CO;2-Z
Régis Mendonça, André Ferraz, André R Cotrim, Flávio T da Silva, Samuel C Oliveira, None, Development of Mathematical Models for Describing Organosolv Pulping Kinetics of Fungally Pretreated Wood Samples Journal of Wood Chemistry and Technology. ,vol. 19, pp. 99- 114 ,(1999) , 10.1080/02773819909349602