Kinetics of polysaccharide hydrolysis in the acid-catalysed delignification of eucalyptus globulus wood by acetic acid
作者： G. Vázquez , G. Antorrena , J. González
DOI: 10.1007/BF00195266
关键词:
摘要: The influence of operating conditions (temperature, HCl catalyst concentration and time) on the percentage xylose solubilized in acid-catalysed delignification Eucalyptus globulus wood by acetic acid was studied using an incomplete 3 × factorial design. Regression analysis afforded equation satisfactorily correlating experimental results. A kinetic model polysaccharide hydrolysis is proposed which involves two parallel first order reactions: one fast hemicellulose other slower cellulose. Under mild (i.e. at low temperatures concentrations) only reaction occurs, leaving cellulosic fraction as unhydrolysed residue.
springer.com
sci-hub.se 参考文章(11)
Helena Pereira, Variability in the chemical composition of plantation eucalypts (Eucalyptus globulus Labill.) Wood and Fiber Science. ,vol. 20, pp. 82- 90 ,(1988)
B. L. Browning, METHODS OF WOOD CHEMISTRY ,(1967)
Anthony H. Conner, Kinetic Modeling of Hardwood Prehydrolysis. Part I. Xylan Removal by Water Prehydrolysis Wood and Fiber Science. ,vol. 16, pp. 268- 277 ,(1984)
Steven Tirtowidjojo, Kyosti V. Sarkanen, Fernand Pla, Joseph L. McCarthy, Kinetics of Organosolv Delignification in Batch- and Flow-Through Reactors Holzforschung. ,vol. 42, pp. 177- 184 ,(1988) , 10.1515/HFSG.1988.42.3.177
R. Aravamuthan, W. Chen, K. Zargarian, G. April, Chemicals from wood: Prehydrolysis/organosolv methods Biomass. ,vol. 20, pp. 263- 276 ,(1989) , 10.1016/0144-4565(89)90066-8
Peter Albersheim, Donald J. Nevins, Patricia D. English, Arthur Karr, A method for the analysis of sugars in plant cell-wall polysaccharides by gas-liquid chromatography Carbohydrate Research. ,vol. 5, pp. 340- 345 ,(1967) , 10.1016/S0008-6215(00)80510-8
J.P. Marais, J.L. de Wit, G.V. Quicke, A critical examination of the Nelson-Somogyi method for the determination of reducing sugars Analytical Biochemistry. ,vol. 15, pp. 373- 381 ,(1966) , 10.1016/0003-2697(66)90098-4
G. V�zquez, G. Antorrena, J. Gonz�lez, Kinetics of acid-catalysed delignification of Eucalyptus globulus wood by acetic acid Wood Science and Technology. ,vol. 29, pp. 267- 275 ,(1995) , 10.1007/BF00202086
Anthony H. Conner, Linda F. Lorenz, KINETIC MODELING OF HARDWOOD PREHYDROLYSIS. PART III. WATER AND DILUTE ACETIC ACID PREHYDROLYSIS OF SOUTHERN RED OAK Wood and Fiber Science. ,vol. 18, pp. 248- 263 ,(1986)
J.F. Harris, R.W. Scott, E.L. Springer, T.H. Wegner, Factors Influencing Dilute Sulfuric Acid Prehydrolysis of Southern Red Oak Wood Progress in Biomass Conversion. ,vol. 5, pp. 101- 141 ,(1984) , 10.1016/B978-0-12-535905-4.50009-6