Photoluminescence and thermoluminescence study of KCaSO4Cl doped with Dy and Ce synthesized by acid distillation method

作者: Bhushan P. Kore , N.S. Dhoble , S.P. Lochab , S.J. Dhoble

DOI: 10.1016/J.JLUMIN.2013.07.030

关键词:

摘要: Abstract Photoluminescence and thermoluminescence properties of KCaSO 4 Cl doped with dysprosium cerium have been studied. Dy/Ce phosphors were synthesized by the acid distillation method. The samples characterized XRD, SEM, PL TL for structural, morphological luminescence studies. SEM image analysis phosphor shows nearly spherical particles diameter varying between 3–10 μm. In present host Dy 3+ emission at 482 573 nm is observed due to F 9/2 → 6 H 15/2 13/2 transition, respectively, whereas spectra Cl:Ce two bands 307 nm 326 nm are attributed allowed inter configurational transitions from 5d-level 2 5/2 7/2 levels Ce ion. Effect annealing on structure glow curve investigated Cl:Dy phosphors. Thermoluminescence linearity has studied 0.1–9000 Gy dose gamma rays. Linear behavior over a large range 0.1 Gy 170 Gy was found. addition this trap parameters using computerized deconvolution.

参考文章(62)
Yanhui Wang, Jianhui Zhang, Dejian Hou, Hongbin Liang, Pieter Dorenbos, Shuaishuai Sun, Ye Tao, Luminescence of Ce3+ activated NaCaPO4 under VUV-UV and X-ray excitation Optical Materials. ,vol. 34, pp. 1214- 1218 ,(2012) , 10.1016/J.OPTMAT.2012.01.033
Carel W.E. Van Eijk, INORGANIC SCINTILLATORS IN POSITRON EMISSION TOMOGRAPHY Springer, Dordrecht. pp. 259- 274 ,(2006) , 10.1007/1-4020-5093-3_11
P Dorenbos, L Pierron, L Dinca, C W E van Eijk, A Kahn-Harari, B Viana, 4f?5d spectroscopy of Ce3+ in CaBPO5, LiCaPO4 and Li2CaSiO4 Journal of Physics: Condensed Matter. ,vol. 15, pp. 511- 520 ,(2003) , 10.1088/0953-8984/15/3/315
Daniela Parisi, Alessandra Toncelli, Mauro Tonelli, Enrico Cavalli, Enrico Bovero, Alessandro Belletti, Optical spectroscopy of BaY2F8:Dy3+ Journal of Physics: Condensed Matter. ,vol. 17, pp. 2783- 2790 ,(2005) , 10.1088/0953-8984/17/17/028
Luo Daling, Zhang Chunxiang, Deng Zouping, Li Guozhen, Thermoluminescence characteristics of MgSO4:Dy,Mn phosphor Radiation Measurements. ,vol. 30, pp. 59- 63 ,(1999) , 10.1016/S1350-4487(98)00082-1
H.S. Sullasi, M.B. Andrade, W.E.F. Ayta, M. Frade, M.D. Sastry, S. Watanabe, Irradiation for dating Brazilian fish fossil by thermoluminescence and EPR technique Nuclear Instruments & Methods in Physics Research Section B-beam Interactions With Materials and Atoms. ,vol. 213, pp. 756- 760 ,(2004) , 10.1016/S0168-583X(03)01698-7
Panli You, Guangfu Yin, Xianchun Chen, Bo Yue, Zhongbing Huang, Xiaoming Liao, Yadong Yao, Luminescence properties of Dy3+-doped Li2SrSiO4 for NUV-excited white LEDs Optical Materials. ,vol. 33, pp. 1808- 1812 ,(2011) , 10.1016/J.OPTMAT.2011.06.018
I.C. Muñoz, E. Cruz-Zaragoza, A. Favalli, C. Furetta, Thermoluminescence property of LiMgF3 erbium activated phosphor. Applied Radiation and Isotopes. ,vol. 70, pp. 893- 896 ,(2012) , 10.1016/J.APRADISO.2012.02.006
Enhai Song, Weiren Zhao, Xihua Dou, Yanjuan Zhu, Shuangping Yi, Huachu Min, None, Nonradiative energy transfer from Mn2+ to Eu3+ in K2CaP2O7:Mn2+,Eu3+ phosphor Journal of Luminescence. ,vol. 132, pp. 1462- 1467 ,(2012) , 10.1016/J.JLUMIN.2012.01.004