Chemical stability of MgO/CaO/Cr2O3–Al2O3–B2O3–phosphate glasses in solid oxide fuel cell environment

作者: P. H Larsen , P. F James

DOI: 10.1023/A:1004332614379

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摘要: The thermal properties, glass forming tendency and stability in solid oxide fuel cell (SOFC) relevant atmospheres have been determined for four different refractory MgO/CaO/Cr2O3–Al2O3–B2O3 phosphate based glasses. Also, the bonding ability interaction as a function of temperature between glasses La0.8Ca0.22CrO3 interconnect material studied. microstructural characterization elemental analysis reaction couples reveal that interface is closely related to CaO content relative tendency. reactions at 1000°C high or MgO containing compositions occur by liquid phase vapour mechanism, respectively. 1200°C both cases occurs mechanism. © 1998 Chapman & Hall

参考文章(8)
J. D. Carter, M. M. Nasrallah, H. U. Anderson, Liquid phase behaviour in nonstoichiometric calcium-doped lanthanum chromites Journal of Materials Science. ,vol. 31, pp. 157- 163 ,(1996) , 10.1007/BF00355140
F. J. GONZALEZ, J. W. HALLORAN, The Ternary System MgO‐Al2O3‐P2O5 Journal of the American Ceramic Society. ,vol. 63, pp. 599- 600 ,(1980) , 10.1111/J.1151-2916.1980.TB10775.X
Natsuko Sakai, Tatsuya Kawada, Harumi Yokokawa, Masayuki Dokiya, Tomoo Iwata, Thermal expansion of some chromium deficient lanthanum chromites Solid State Ionics. pp. 394- 397 ,(1990) , 10.1016/0167-2738(90)90365-X
Akira Kishioka, Masao Hayashi, Makio Kinoshita, Glass Formation and Crystallization in Ternary Phosphate Systems Containing Al2O3 Bulletin of the Chemical Society of Japan. ,vol. 49, pp. 3032- 3036 ,(1976) , 10.1246/BCSJ.49.3032
Teruhisa Horita, Jin-Sam Choi, You-Kee Lee, Natsuko Sakai, Tatsuya Kawada, Harumi Yokokawa, Masayuki Dokiya, Reaction between Calcium‐Doped Lanthanum Chromite and Silica Journal of the American Ceramic Society. ,vol. 78, pp. 1729- 1756 ,(1995) , 10.1111/J.1151-2916.1995.TB08882.X
K. L. Ley, M. Krumpelt, R. Kumar, J. H. Meiser, I. Bloom, Glass-ceramic sealants for solid oxide fuel cells: Part I. Physical properties Journal of Materials Research. ,vol. 11, pp. 1489- 1493 ,(1996) , 10.1557/JMR.1996.0185
Natsuko Sakai, Tatsuya Kawada, Harumi Yokokawa, Masayuki Dokiya, Isao Kojima, Liquid‐Phase‐Assisted Sintering of Calcium‐Doped Lanthanum Chromites Journal of the American Ceramic Society. ,vol. 76, pp. 609- 616 ,(1993) , 10.1111/J.1151-2916.1993.TB03649.X
M. Ouchetto, B. Elouadi, S. Parke, Study of lanthanide zinc phosphate glasses by differential thermal analysis Physics and Chemistry of Glasses. ,vol. 32, pp. 22- 28 ,(1991)