Interfacial kinetics of a model epoxy-amine addition reaction.

作者: Tomoyasu Hirai , Kaoru Kawasaki , Keiji Tanaka

DOI: 10.1039/C2CP42673K

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摘要: The kinetics of the addition reaction at a solid interface for model epoxy–amine system composed monofunctionalized phenyl glycidyl ether and hexylamine was examined. chemical character this same as that in bulk, while physical nature significantly different. Slowing down diffusion reactants close proximity to also addressed by interfacial selective spectroscopy.

参考文章(27)
Jovan Mijović, Saša Andjelić, Monitoring of reactive processing by remote mid infra-red spectroscopy Polymer. ,vol. 37, pp. 1295- 1303 ,(1996) , 10.1016/0032-3861(96)81124-4
Fred C. McCormick, Moisture effects upon the dimensional stability of an S-glass/epoxy composite Polymer Engineering and Science. ,vol. 19, pp. 359- 364 ,(1979) , 10.1002/PEN.760190507
S. Sourour, M.R. Kamal, Differential scanning calorimetry of epoxy cure: isothermal cure kinetics☆ Thermochimica Acta. ,vol. 14, pp. 41- 59 ,(1976) , 10.1016/0040-6031(76)80056-1
J.Y Lee, H.K Choi, M.J Shim, S.W Kim, Kinetic studies of an epoxy cure reaction by isothermal DSC analysis Thermochimica Acta. ,vol. 343, pp. 111- 117 ,(2000) , 10.1016/S0040-6031(99)00303-2
Senen Paz-Abuin, Arturo Lopez-Quintela, Montse Varela, Mercedes Pazos-Pellin, Pilar Prendes, Method for determination of the ratio of rate constants, secondary to primary amine, in epoxy-amine systems Polymer. ,vol. 38, pp. 3117- 3120 ,(1997) , 10.1016/S0032-3861(96)01093-2
Z. Yang, Y. Fujii, F. K. Lee, C.-H. Lam, O. K. C. Tsui, Glass Transition Dynamics and Surface Layer Mobility in Unentangled Polystyrene Films Science. ,vol. 328, pp. 1676- 1679 ,(2010) , 10.1126/SCIENCE.1184394
Carmen C. Riccardi, Roberto J. J. Williams, A kinetic scheme for an amine-epoxy reaction with simultaneous etherification Journal of Applied Polymer Science. ,vol. 32, pp. 3445- 3456 ,(1986) , 10.1002/APP.1986.070320208