Aliphatische α-substituierte Nitroso-Verbindungen, I. Zur Chemie und Stereochemie von α-substituierten 3-Nitrosomenthanen
作者： Günter Kresze , Norbert Michael Mayer , Johannes Winkler
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摘要: 3-Nitroso-3-halogen- bzw. 3-Nitroso-3-acyloxy-menthane 2 werden dargestellt. Ihre Isomerisierung zu den Diastereomeren 6 und die Substitution des Halogens untersucht. UV- NMR-Spektren sowie CD-Kurven der 3-Nitroso-menthane Aussagen uber Stereochemie benutzt (Tabb. 1–4, Abb. 1 2). Aliphatic α-Substituted Nitroso Compounds, I. Chemistry and Stereochemistry of 3-Nitrosomenthanes 3-Nitroso-3-halo- or 3-nitroso-3-acyloxymenthanes are prepared. Their isomerisation to the diastereoisomeric substitution reactions halogen derivatives investigated. NMR-spectra as well CD-curves nitrosomenthanes used obtain information about stereochemistry these compounds (tables figures 2).
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