Evidence of ironmercury bonds in complexes of ferrocene with mercuric chloride from mössbauer spectroscopy

作者: Roger M.G. Roberts , Jack Silver , Ian E.G. Morrison

DOI: 10.1016/S0022-328X(00)81194-8

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摘要: Abstract Novel Mossbauer spectra of ferrocene/mercuric chloride adducts are reported, displaying anomalously high quadrupole splittings, which interpreted as strong evidence for FeHg bonding. The results discussed in conjunction with tilting the cyclopentadienyl rings.

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