Partial oxidation of methane with nitrous oxide forms synthesis gas over cobalt exchanged ZSM-5
作者： Naseer A. Khan , Eric M. Kennedy , Bogdan Z. Dlugogorski , Adesoji A. Adesina , Michael Stockenhuber
DOI: 10.1016/J.CATCOM.2014.04.012
关键词:
摘要: Synthesis gas (CO + H2) is a versatile and significant resource. In this communication we show that cobalt loaded on ZSM-5 (Co-ZSM-5) catalyses the formation of synthesis from CH4, under partial oxidation conditions using N2O as oxidant. With O2 oxidant over same Co-ZSM-5 catalyst, alumina Fe-ZSM-5, only COx H2O are formed. Isolated Co2 sites in support proposed active for H2 (synthesis gas) formation.
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