作者: W. Rudziński , K. Nieszporek , A. Dabrowski
DOI: 10.1177/0263617499010001-405
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摘要: The new theoretical approach to multisite-occupancy adsorption on heterogeneous surfaces, developed recently by Rudzinski and Everett, is generalized for the case of systems characterized non-Gaussian energy distributions. Attention focused distribution which, in one-site -occupancy adsorption, leads Dubinin-Astakhov isotherm equation. In effect, a form that equation common actual systems. sensitive surface topography; hence, fitting it experimental isotherms creates chance study topography carbonaceous surfaces. An example such computer exercises reported here before more systematic published.