Oxidation of hydrocarbons. 18. Mechanism of the reaction between permanganate and carbon-carbon double bonds

摘要: The nature of the products obtained when permanganate reacts with olefins is determined by rapid reactions that occur after rate-limiting step (which known to involve formation an intermediate cyclic manganate(V) diester). A study oxide has shown its primary are disproportionation and oxidation manganate(VI) permanganate. Disproportionation slow under highly basic conditions very moderately or neutral conditions. converse true for reaction between Consequently, although principle diester likely conditions, in solutions. It how these kinetic measurements account observed products-diols solutions ketols