The Experimental Thermochemistry of Metal Phenolates
作者： Suzanne W. Slayden , Joel F. Liebman
DOI: 10.1002/9780470682531.PAT0601
关键词:
摘要: The current study concerns the thermochemistry of metal phenolates wherein is bound to oxygen by a σ bond, or part an ionic solid salt ion pairs in solution. main quantities that are discussed enthalpies formation and binding, equilibrium stability constants. discussion organized increasing atomic number metals, starting with lithium ending actinides. Complete coverage not intended, but at least one rationalized thermochemical example for each given, where such data exists. Keywords: binding constants; complexes; chelates; enthalpy formation; enthalpy reaction; equilibrium constants; periodic trends; redox electrode potentials; stability constants
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