Gas Permeability of Hexaphenylbenzene Based Polymers of Intrinsic Microporosity
作者： Mariolino Carta , Paola Bernardo , Gabriele Clarizia , Johannes C. Jansen , Neil B. McKeown
DOI: 10.1021/MA501925J
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摘要: The synthesis and characterization of a series novel hexaphenylbenzene (HPB) based polymers intrinsic microporosity (PIM-HPBs) containing methyl, bromine, nitrile substituents are reported. successful formation thin films from these allowed the evaluation influence on gas permeability. Analysis by time-lag method also yielded information about diffusion coefficients and, indirectly, solubility. permeability varies as function polarity shows significant increase after treatment samples with methanol, especially for cast THF solvent. This enhancement, which is mostly due to an in coefficient, only partially lost upon aging membranes 5 months. Measurements at different feed pressures confirm typical dual mode sorption behavior, increasing diffusivity decreasing solubility fun...
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sci-hub.se 参考文章(85)
H.D. Dakin, Randolph West, SOME AROMATIC DERIVATIVES OF SUBSTITUTED ACETYLAMINOACETONES Journal of Biological Chemistry. ,vol. 78, pp. 757- 764 ,(1928) , 10.1016/S0021-9258(18)83979-5
Helen J. Mackintosh, Peter M. Budd, Neil B. McKeown, Catalysis by microporous phthalocyanine and porphyrin network polymers Journal of Materials Chemistry. ,vol. 18, pp. 573- 578 ,(2008) , 10.1039/B715660J
Naiying Du, Gilles P. Robertson, Jingshe Song, Ingo Pinnau, Michael D. Guiver, High-Performance Carboxylated Polymers of Intrinsic Microporosity (PIMs) with Tunable Gas Transport Properties† Macromolecules. ,vol. 42, pp. 6038- 6043 ,(2009) , 10.1021/MA9009017
Mariolino Carta, Kadhum J. Msayib, Peter M. Budd, Neil B. McKeown, Novel spirobisindanes for use as precursors to polymers of intrinsic microporosity Organic Letters. ,vol. 10, pp. 2641- 2643 ,(2008) , 10.1021/OL800573M
Rhys Short, Mariolino Carta, C. Grazia Bezzu, Detlev Fritsch, Benson M. Kariuki, Neil B. McKeown, Hexaphenylbenzene-based polymers of intrinsic microporosity Chemical Communications. ,vol. 47, pp. 6822- 6824 ,(2011) , 10.1039/C1CC11717C
Yugen Zhang, Siti Nurhanna Riduan, Functional porous organic polymers for heterogeneous catalysis Chem. Soc. Rev.. ,vol. 41, pp. 2083- 2094 ,(2012) , 10.1039/C1CS15227K
Kenneth E. Maly, Eric Gagnon, Thierry Maris, James D. Wuest, Engineering hydrogen-bonded molecular crystals built from derivatives of hexaphenylbenzene and related compounds. Journal of the American Chemical Society. ,vol. 129, pp. 4306- 4322 ,(2007) , 10.1021/JA067571X
J. C. J. Bart, The crystal structure of a modification of hexaphenylbenzene Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. ,vol. 24, pp. 1277- 1287 ,(1968) , 10.1107/S0567740868004176
Jingshe Song, Naiying Du, Ying Dai, Gilles P. Robertson, Michael D. Guiver, Sylvie Thomas, Ingo Pinnau, Linear High Molecular Weight Ladder Polymers by Optimized Polycondensation of Tetrahydroxytetramethylspirobisindane and 1,4-Dicyanotetrafluorobenzene† Macromolecules. ,vol. 41, pp. 7411- 7417 ,(2008) , 10.1021/MA801000U
H. B. Park, C. H. Jung, Y. M. Lee, A. J. Hill, S. J. Pas, S. T. Mudie, E. Van Wagner, B. D. Freeman, D. J. Cookson, Polymers with Cavities Tuned for Fast Selective Transport of Small Molecules and Ions Science. ,vol. 318, pp. 254- 258 ,(2007) , 10.1126/SCIENCE.1146744