Intrinsically Microporous Polymer Retains Porosity in Vacuum Thermolysis to Electroactive Heterocarbon.
作者： Yuanyang Rong , Daping He , Adrian Sanchez-Fernandez , Craig Evans , Karen J. Edler
DOI: 10.1021/ACS.LANGMUIR.5B02654
关键词:
摘要: Vacuum carbonization of organic precursors usually causes considerable structural damage and collapse of morphological features. However, for a polymer with intrinsic microporosity (PIM-EA-TB with a Brunauer–Emmet–Teller (BET) surface area of 1027 m²g–¹), it is shown here that the rigidity of the molecular backbone is retained even during 500° C vacuum carbonization, yielding a novel type of microporous heterocarbon (either as powder or as thin film membrane) with properties between those of a conducting polymer and those of a …
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