A Comparative Spectrophotometric Study Using Ferrozine and 1,10-Ortho-phenanthroline to Evaluate the Iron Redox Ratio (Fe(2+)/ΣFe) in Glass Prepared by Microwave Heating.
作者： Biswajit MANDAL , Prasanta Kumar SINHA , Ranjan SEN , Ashis Kumar MANDAL
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摘要: In the present study, Fe-doped barium borosilicate glass has been melted at 1250 degrees C under microwave heating. The iron redox ratio (Fe2+/total Fe) in is investigated by two spectrophotometric methods. A novel decomposition technique optimized to measure ferrous oxidation state glass. Ferrozine was chosen as a specific complexing reagent; it forms deep violet color complex with Fe2+ and broad absorbance peak centered 562 nm. 1,10-ortho-phenanthroline develops an orange (having similar 510 nm) used determine ion Both methods are compared estimated found be higher ferrozine method. error limit of measurement determined 0.012 0.023 for methods, respectively.
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Andrea Ceglia, Gert Nuyts, Wendy Meulebroeck, Simone Cagno, Alberta Silvestri, Alfonso Zoleo, Karin Nys, Koen Janssens, Hugo Thienpont, Herman Terryn, Iron speciation in soda-lime-silica glass: a comparison of XANES and UV-vis-NIR spectroscopy Journal of Analytical Atomic Spectrometry. ,vol. 30, pp. 1552- 1561 ,(2015) , 10.1039/C5JA00046G
Jun-Sik Jeoung, W. Howard Poisl, Michael C. Weinberg, Gary L. Smith, Hong Li, Effect of Oxidation State of Iron on Phase Separation in Sodium Silicate Glasses Journal of the American Ceramic Society. ,vol. 84, pp. 1859- 1864 ,(2004) , 10.1111/J.1151-2916.2001.TB00927.X
P.A. Bingham, J.M. Parker, T.M. Searle, I. Smith, Local structure and medium range ordering of tetrahedrally coordinated Fe3+ ions in alkali–alkaline earth–silica glasses Journal of Non-crystalline Solids. ,vol. 353, pp. 2479- 2494 ,(2007) , 10.1016/J.JNONCRYSOL.2007.03.017
Ashis K. Mandal, Prasanta K. Sinha, Dipankar Das, Chandan Guha, Ranjan Sen, Higher Fe2+/total Fe ratio in iron doped phosphate glass melted by microwave heating Materials Research Bulletin. ,vol. 63, pp. 141- 146 ,(2015) , 10.1016/J.MATERRESBULL.2014.11.052
PAUL CLOSE, H. M. SHEPHERD, C. H. DRUMMOND, Determination of Several Valences of Iron, Arsenic and Antimony, and Selenium in Glass Journal of the American Ceramic Society. ,vol. 41, pp. 455- 460 ,(1958) , 10.1111/J.1151-2916.1958.TB12894.X
Christelle Marlet, Georges Lognay, Development and validation by accuracy profile of a method for the analysis of monoterpenes in indoor air by active sampling and thermal desorption-gas chromatography-mass spectrometry. Talanta. ,vol. 82, pp. 1230- 1239 ,(2010) , 10.1016/J.TALANTA.2010.06.044
L.B Glebov, E.N Boulos, Absorption of iron and water in the Na2O-CaO-MgO-SiO2 glasses. II. Selection of intrinsic, ferric, and ferrous spectra in the visible and UV regions Journal of Non-crystalline Solids. ,vol. 242, pp. 49- 62 ,(1998) , 10.1016/S0022-3093(98)00776-5
Jaroslava Švarc-Gajić, Zorica Stojanović, Selenium determination in biscuits and pasta: development of chronopotentiometric stripping determination by using a sulphide as an internal standard. Talanta. ,vol. 115, pp. 474- 481 ,(2013) , 10.1016/J.TALANTA.2013.06.005
A. D. Wilson, The micro-determination of ferrous iron in silicate minerals by a volumetric and a colorimetric method The Analyst. ,vol. 85, pp. 823- 827 ,(1960) , 10.1039/AN9608500823
L. Ghussn, J. R. Martinelli, A novel method to produce niobium phosphate glasses by microwave heating Journal of Materials Science. ,vol. 39, pp. 1371- 1376 ,(2004) , 10.1023/B:JMSC.0000013899.75724.E1