Three-Strand Conducting Ladder Polymers: Two-Step Electropolymerization of Metallorotaxanes
作者： Julio Buey , Timothy M. Swager
DOI: 10.1002/(SICI)1521-3773(20000204)39:3<608::AID-ANIE608>3.0.CO;2-W
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摘要: Sequential polymerization of supramolecular metallorotaxane complexes results in three-stranded conducting ladder polymers. The internal polymer is "sandwiched" between the other two polymers to give molecular wires that are effectively insulated when outer their nonconducting state (shown schematically). intermolecular conductivity can be mediated by Cu(1+)/Cu(2+) redox couple.
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