The effects of the location of organoclay on the structure and mechanical properties of compatibilized polypropylene/polyamide‐12 ternary nanocomposites

作者: N. Aranburu , J. I. Eguiazábal , G. Guerrica-Echevarria

DOI: 10.1002/PEN.24631

关键词:

摘要: Ternary nanocomposites (NCs) were obtained by melt-mixing maleic anhydride-modified polypropylene (gPP) with previously prepared polyamide-12 (PA12)/organically modified montmorillonite (OMMT) NCs. During melt-mixing, OMMT migrated from the PA12 phase to gPP/PA12 interphase. Moreover, a critical concentration of was found saturate interphase and, at higher contents, excess gPP matrix. When compared unfilled blends, addition caused change in microstructure. The average size dispersed particles NCs be independent content. At contents below concentration, that is, when located interphase, Young's modulus remained practically unchanged and ductile nature ternary maintained. However, increased linearly became brittle, due presence POLYM. ENG. SCI., 2017. © 2017 Society Plastics Engineers

参考文章(52)
Izaro Goitisolo, Imanol González, José Ignacio Eguiazábal, Effects of the location of the nanoclay at the interface on the mechanical properties of a maleic anhydride grafted polypropylene/polyamide 6/organoclay co‐continuous blend Polymers for Advanced Technologies. ,vol. 24, pp. 357- 363 ,(2013) , 10.1002/PAT.3085
Mei-Ling Xue, Peng Li, Phase morphology and clay distribution of poly(trimethylene terephthalate)/polypropylene/montmorillonite nanocomposites Journal of Applied Polymer Science. ,vol. 113, pp. 3883- 3890 ,(2009) , 10.1002/APP.30417
C CALCAGNO, C MARIANI, S TEIXEIRA, R MAULER, The role of the MMT on the morphology and mechanical properties of the PP/PET blends Composites Science and Technology. ,vol. 68, pp. 2193- 2200 ,(2008) , 10.1016/J.COMPSCITECH.2008.03.012
G. Guerrica-Echevarrı́a, J.I. Eguiazábal, J. Nazábal, Interfacial tension as a parameter to characterize the miscibility level of polymer blends Polymer Testing. ,vol. 19, pp. 849- 854 ,(2000) , 10.1016/S0142-9418(99)00055-0
T.D Fornes, P.J Yoon, D.L Hunter, H Keskkula, D.R Paul, Effect of organoclay structure on nylon 6 nanocomposite morphology and properties Polymer. ,vol. 43, pp. 5915- 5933 ,(2002) , 10.1016/S0032-3861(02)00400-7
S. Malmir, M. K. Razavi Aghjeh, M. Hemmati, R. Ahmadi Tehrani, Relationship between morphology and rheology of PA/PE/Clay blend nanocomposites. I. PA matrix Journal of Applied Polymer Science. ,vol. 125, ,(2012) , 10.1002/APP.36439
Min Ho Lee, Cheol Ho Dan, Jeong Ho Kim, Jaehyug Cha, Seonglyong Kim, Yongyeon Hwang, Chan Hong Lee, Effect of clay on the morphology and properties of PMMA/poly(styrene-co-acrylonitrile)/clay nanocomposites prepared by melt mixing Polymer. ,vol. 47, pp. 4359- 4369 ,(2006) , 10.1016/J.POLYMER.2006.04.003
Fang-Chyou Chiu, Cheng-En Lee, Chen-Tsyr Lo, Fabrication and comparison of PP (blend)-based (nano)composites—Effect of PP matrix flow property Materials Chemistry and Physics. ,vol. 139, pp. 580- 589 ,(2013) , 10.1016/J.MATCHEMPHYS.2013.01.060
G. Filippone, N.Tz. Dintcheva, D. Acierno, F.P. La Mantia, The role of organoclay in promoting co-continuous morphology in high-density poly(ethylene)/poly(amide) 6 blends Polymer. ,vol. 49, pp. 1312- 1322 ,(2008) , 10.1016/J.POLYMER.2008.01.045
Pascal Médéric, Julien Ville, Jacques Huitric, Michel Moan, Thierry Aubry, Effect of processing procedures and conditions on structural, morphological, and rheological properties of polyethylene/polyamide/nanoclay blends Polymer Engineering & Science. ,vol. 51, pp. 969- 978 ,(2011) , 10.1002/PEN.21825