Synthesis and Structure of a Trinuclear Rhenium Cluster Complex [PEt3H][Re3(μ3-S)(μ-S)3Cl6(PEt3)3]

作者: Naofumi Miyake , Hideo Imoto , Taro Saito

DOI: 10.1246/CL.1997.913

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摘要: Reaction of [Re3(μ3-S)(μ-S2)3Cl6]Cl with triethylphosphine in benzene formed [PEt3H][Re3(μ3-S)(μ-S)3Cl6(PEt3)3]. The triangular cluster has eight metal electrons and the core resembles that [Mo3(μ3-S)(μ-S)3Cl4L5] complexes.

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