作者: Taro Saito , Hideo Imoto
DOI: 10.1246/BCSJ.69.2403
关键词: Rhenium 、 Chemistry 、 Physical chemistry 、 Valence electron 、 Chromium 、 Molybdenum 、 Inorganic chemistry 、 Tungsten 、 Chalcogenide 、 Cluster (physics)
摘要: Trinuclear, tetranuclear, hexanuclear, and dodecanuclear chalcogenide cluster complexes of chromium, molybdenum, tungsten, rhenium have been synthesized their molecular electronic structures characterized. The structure-cluster valence electron relationships are analyzed a new isoelectronic analogy is proposed.