An algorithm for simulation of electrochemical systems with surface-bulk coupling strategies

摘要: In Buoni and Petzold (2007) [13] we described a new algorithm for simulation of electrochemical systems on two-dimensional irregular, time-dependent domains. Here show how to extend the three dimensions. We demonstrate our three-dimensional by simulating copper electrodeposition into via structure. This problem poses challenges coupling dilute electrolyte (bulk) model surface dynamics model, which involves complex network reactions. To handle this coupling, introduce highly effective semi-implicit method.