Characterization of palladium and palladium-silver alloy layers on stainless steel support

作者: MASAHIRO KATOH , AKIRA SONDOH , TOSHIHIDE HORIKAWA , TAHEI TOMIDA

DOI: 10.1142/S0217979206040507

关键词:

摘要: Pd and Pd/Ag layers were prepared by a technique of electroless plating on stainless steel supports. To form layers, layer was plated an activated (SS) sheet followed Ag plating. The Pd/Ag-SS composite annealed at 873 K-973 K for 10 h -12 in helium. Before annealing, the thickness 7.6 μm 1.9 μm, respectively. formation alloy observed SS after annealing 12 ratios Ag/(Pd+Ag) 0.28 surface XRF 0.29 bulk XPS. This result showed homogeneous that condition. Helium permeances measured pressure difference 1 atm room temperature. porous (PSS) tubes without with 78 100 m3/m2h 0.35 m3/m2h, obtained membrane almost dense membrane.

参考文章(7)
T OZAKI, Y ZHANG, M KOMAKI, C NISHIMURA, Preparation of palladium-coated V and V–15Ni membranes for hydrogen purification by electroless plating technique International Journal of Hydrogen Energy. ,vol. 28, pp. 297- 302 ,(2003) , 10.1016/S0360-3199(02)00065-4
Shigeyuki Uemiya, Noboru Sato, Hiroshi Ando, Yukinori Kude, Takeshi Matsuda, Eiichi Kikuchi, Separation of hydrogen through palladium thin film supported on a porous glass tube Journal of Membrane Science. ,vol. 56, pp. 303- 313 ,(1991) , 10.1016/S0376-7388(00)83040-9
Peter P. Mardilovich, Ying She, Yi Hua Ma, Min-Hon Rei, Defect‐free palladium membranes on porous stainless‐steel support Aiche Journal. ,vol. 44, pp. 310- 322 ,(1998) , 10.1002/AIC.690440209
Yi Hua Ma, B. Ceylan Akis, M. Engin Ayturk, Federico Guazzone, Erik E. Engwall, Ivan P. Mardilovich, Characterization of Intermetallic Diffusion Barrier and Alloy Formation for Pd/Cu and Pd/Ag Porous Stainless Steel Composite Membranes Industrial & Engineering Chemistry Research. ,vol. 43, pp. 2936- 2945 ,(2004) , 10.1021/IE034002E
S Tosti, Rolled thin Pd and Pd–Ag membranes for hydrogen separation and production International Journal of Hydrogen Energy. ,vol. 25, pp. 319- 325 ,(2000) , 10.1016/S0360-3199(99)00044-0
Y.S. Cheng, K.L. Yeung, Palladium-silver composite membranes by electroless plating technique Journal of Membrane Science. ,vol. 158, pp. 127- 141 ,(1999) , 10.1016/S0376-7388(99)00009-5