Quasi-block copolymer libraries on demand via sequential RAFT polymerization in an automated parallel synthesizer
作者： Carlos Guerrero-Sanchez , Lisa O'Brien , Colin Brackley , Daniel J. Keddie , Simon Saubern
DOI: 10.1039/C3PY21135E
关键词:
摘要: A convenient synthetic method for the systematic preparation of quasi-diblock copolymer libraries utilizing a sequential RAFT polymerization strategy is described. This utilizes parallel synthesizer and allows unattended fully automated synthesis this type library in short period time. The materials obtained investigation have shown properties very similar to those expected “pure” diblock copolymers as determined by differential scanning calorimetry. described can be useful less expensive alternative rapid screening block libraries.
rsc.org
sci-hub.se 参考文章(37)
US Ulrich Schubert, CA Carlos Guerrero-Sanchez, Experimental techniques in (parallel) anionic polymerizations : an overview Chimica Oggi-chemistry Today. ,vol. 23, pp. 34- 38 ,(2005)
Dean C. Webster, Michael A. R. Meier, Polymer Libraries: Preparation and Applications Advances in Polymer Science. ,vol. 225, pp. 1- 15 ,(2009) , 10.1007/12_2009_15
Tracey M. Hinton, Carlos Guerrero-Sanchez, Janease E. Graham, Tam Le, Benjamin W. Muir, Shuning Shi, Mark L.V. Tizard, Pathiraja A. Gunatillake, Keith M. McLean, San H. Thang, The effect of RAFT-derived cationic block copolymer structure on gene silencing efficiency Biomaterials. ,vol. 33, pp. 7631- 7642 ,(2012) , 10.1016/J.BIOMATERIALS.2012.06.090
Frederik Wurm, Holger Frey, Linear-dendritic block copolymers: The state of the art and exciting perspectives Progress in Polymer Science. ,vol. 36, pp. 1- 52 ,(2011) , 10.1016/J.PROGPOLYMSCI.2010.07.009
Pascal Chapon, Catherine Mignaud, Gilda Lizarraga, Mathias Destarac, Automated Parallel Synthesis of MADIX (Co)Polymers Macromolecular Rapid Communications. ,vol. 24, pp. 87- 91 ,(2003) , 10.1002/MARC.200390016
Julie N.L. Albert, Thomas H. Epps, Self-assembly of block copolymer thin films Materials Today. ,vol. 13, pp. 24- 33 ,(2010) , 10.1016/S1369-7021(10)70106-1
Carlos Guerrero-Sanchez, Daan Wouters, Charles-André Fustin, Jean-François Gohy, Bas G. G. Lohmeijer, Ulrich S. Schubert, Structure-Property Study of Diblock Copolymer Micelles: Core and Corona Radius with Varying Composition and Degree of Polymerization Macromolecules. ,vol. 38, pp. 10185- 10191 ,(2005) , 10.1021/MA051544U
Shinji Sugihara, Shin-Ichiro Matsuzono, Hideki Sakai, Masahiko Abe, Sadahito Aoshima, Syntheses of amphiphilic block copolymers by living cationic polymerization of vinyl ethers and their selective solvent‐induced physical gelation Journal of Polymer Science Part A. ,vol. 39, pp. 3190- 3197 ,(2001) , 10.1002/POLA.1301
Abdullah Ekin, Dean C. Webster, Synthesis and Characterization of Novel Hydroxyalkyl Carbamate and Dihydroxyalkyl Carbamate Terminated Poly(dimethylsiloxane) Oligomers and Their Block Copolymers with Poly(∊-caprolactone) Macromolecules. ,vol. 39, pp. 8659- 8668 ,(2006) , 10.1021/MA061629A
Christina Ott, Georges M. Pavlov, Carlos Guerrero-Sanchez, Ulrich S. Schubert, Alternating terpyridine-endfunctionalized copolymers of styrene and diphenylethylene via anionic polymerization techniques: A detailed characterization study Journal of Polymer Science Part A: Polymer Chemistry. ,vol. 47, pp. 3691- 3701 ,(2009) , 10.1002/POLA.23407