Silver nanoparticles-embedded poly(1-naphthylamine) nanospheres for low-cost non-enzymatic electrochemical H 2 O 2 sensor

作者: Femina Kanjirathamthadathil Saidu , Alex Joseph , Eldhose Vadakkechalil Varghese , George Vazhathara Thomas

DOI: 10.1007/S00289-019-03053-X

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摘要: In this work, a novel nanocomposite containing silver nanoparticles (AgNPs) embedded poly(1-naphthylamine) nanospheres (Ag/PNA) was prepared by in situ chemical reduction of nitrate. The structure, composition, and morphology the Ag/PNA nanocomposites were established Fourier transform infrared spectrometry, X-ray diffraction, scanning electron microscopy, transmission microscopy. electrochemical properties PNA Ag/PNA-modified carbon paste electrodes analyzed using cyclic voltammetry (cyclic voltammogram) impedance spectroscopy. It is observed that charge transfer characteristics have significantly enhanced upon incorporation AgNPs. has shown impressive electrocatalytic sensing performance toward H2O2. Remarkably, present Ag/PNA-based enzymeless voltammetric H2O2 sensor showed wide detection range concentration 1–3000 μM with lower limit 0.972 μM. study revealed are an ideal platform for fabrication low-cost non-enzymatic high sensitivity, good reproducibility, better selectivity, stability.

参考文章(63)
Junwei Ding, Kai Zhang, Gang Wei, Zhiqiang Su, Fabrication of polypyrrole nanoplates decorated with silver and gold nanoparticles for sensor applications RSC Advances. ,vol. 5, pp. 69745- 69752 ,(2015) , 10.1039/C5RA10370C
Yancai Li, Yayun Zhang, Yanmei Zhong, Shunxing Li, Enzyme-free hydrogen peroxide sensor based on Au@Ag@C core-double shell nanocomposites Applied Surface Science. ,vol. 347, pp. 428- 434 ,(2015) , 10.1016/J.APSUSC.2015.04.102
Natalia V. Blinova, Jaroslav Stejskal, Miroslava Trchová, Irina Sapurina, Gordana Ćirić-Marjanović, The oxidation of aniline with silver nitrate to polyaniline–silver composites Polymer. ,vol. 50, pp. 50- 56 ,(2009) , 10.1016/J.POLYMER.2008.10.040
Patrycja Bober, Jaroslav Stejskal, Miroslava Trchová, Jan Prokeš, Irina Sapurina, Oxidation of Aniline with Silver Nitrate Accelerated by p-Phenylenediamine: A New Route to Conducting Composites Macromolecules. ,vol. 43, pp. 10406- 10413 ,(2010) , 10.1021/MA101474J
Ufana Riaz, Sharif Ahmad, S Marghoob Ashraf, None, Effect of Dopant on the Nanostructured Morphology of Poly (1-naphthylamine) Synthesized by Template Free Method Nanoscale Research Letters. ,vol. 3, pp. 45- 48 ,(2008) , 10.1007/S11671-007-9112-2
J. Upadhyay, A. Kumar, B. Gogoi, A.K. Buragohain, Antibacterial and hemolysis activity of polypyrrole nanotubes decorated with silver nanoparticles by an in-situ reduction process. Materials Science and Engineering: C. ,vol. 54, pp. 8- 13 ,(2015) , 10.1016/J.MSEC.2015.04.027
Kun Tian, Megan Prestgard, Ashutosh Tiwari, A review of recent advances in nonenzymatic glucose sensors. Materials Science and Engineering: C. ,vol. 41, pp. 100- 118 ,(2014) , 10.1016/J.MSEC.2014.04.013
Pengshu Wang, Jiayang Xiao, Manman Guo, Yue Xia, Zelin Li, Xiaochun Jiang, Wei Huang, Voltammetric Determination of 4-Nitrophenol at Graphite Nanoflakes Modified Glassy Carbon Electrode Journal of The Electrochemical Society. ,vol. 162, ,(2015) , 10.1149/2.0991501JES