Highly sensitive and selective naked-eye detection of Cu2+ in aqueous medium by a ninhydrin–quinoxaline derivative
作者： Ajit Kumar , Virendra Kumar , Uzra Diwan , K.K. Upadhyay
DOI: 10.1016/J.SNB.2012.09.089
关键词:
摘要: Abstract A simple ninhydrin–quinoxaline based colorimetric receptor 1 was designed, synthesized and characterized. The same exhibited high sensitivity selectivity towards Cu 2+ in aqueous medium (ethanol:H 2 O, 1:9, v/v) over a wide variation of cations such as Na + , Mg Al 3+ Co Fe Ni Zn Cd Hg Pb . addition to the solution gave clear colour change from olive green pink. detection limit found be 3.43 × 10 −7 M which is probably lowest one for an by any naked-eye till date. specificity along with control compound were investigated detail. This only second report where ninhydrin used construction sensor.
elsevier.com
sci-hub.se 参考文章(42)
Eleanor Crabb, Lesley Smart, Elaine Moore, Concepts in transition metal chemistry Royal Society of Chemistry. ,(2010)
J. J. R. Fraústo da Silva, The Biological Chemistry of the Elements: The Inorganic Chemistry of Life ,(2001)
Kerim M. Gattás-Asfura, Roger M. Leblanc, Peptide-coated CdS quantum dots for the optical detection of copper(ii) and silver(i) Chem. Commun.. pp. 2684- 2685 ,(2003) , 10.1039/B308991F
Robert B. Jonas, Acute Copper and Cupric Ion Toxicity in an Estuarine Microbial Community Applied and Environmental Microbiology. ,vol. 55, pp. 43- 49 ,(1989) , 10.1128/AEM.55.1.43-49.1989
Xing Ma, Zhuowei Tan, Guohua Wei, Dongbin Wei, Yuguo Du, Solvent controlled sugar–rhodamine fluorescence sensor for Cu2+ detection Analyst. ,vol. 137, pp. 1436- 1439 ,(2012) , 10.1039/C2AN16155A
Guangjie He, Xiuwen Zhao, Xiaolin Zhang, Hongjun Fan, Shuo Wu, Huaqiang Li, Cheng He, Chunying Duan, A turn-on PET fluorescence sensor for imaging Cu2+ in living cells New Journal of Chemistry. ,vol. 34, pp. 1055- 1058 ,(2010) , 10.1039/C0NJ00132E
Weiying Lin, Lin Yuan, Wen Tan, Jianbo Feng, Lingliang Long, Construction of Fluorescent Probes Via Protection/Deprotection of Functional Groups: A Ratiometric Fluorescent Probe for Cu2+ Chemistry: A European Journal. ,vol. 15, pp. 1030- 1035 ,(2009) , 10.1002/CHEM.200801501
Paramjit Kaur, Mandeep Kaur, Kamaljit Singh, Ferrocene based chemosensor for Cu2+—A dual channel signaling system Talanta. ,vol. 85, pp. 1050- 1055 ,(2011) , 10.1016/J.TALANTA.2011.05.026
K.K. Upadhyay, Ajit Kumar, Jianzhang Zhao, Rakesh K. Mishra, Naked-eye recognition of CuII, ZnII and acetate ion by the first guanine-based difunctional chromoinophore Talanta. ,vol. 81, pp. 714- 721 ,(2010) , 10.1016/J.TALANTA.2010.01.005
Honglei Mu, Rui Gong, Qiao Ma, Yimin Sun, Enqin Fu, A novel colorimetric and fluorescent chemosensor: synthesis and selective detection for Cu2+ and Hg2+ Tetrahedron Letters. ,vol. 48, pp. 5525- 5529 ,(2007) , 10.1016/J.TETLET.2007.05.155