Electrical, magnetic, and EPR studies of the quaternary chalcogenides Cu2AIIBIVX4 prepared by iodine transport
作者： L. Guen , W.S. Glaunsinger
DOI: 10.1016/0022-4596(80)90457-0
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摘要: Abstract Electrical, magnetic, and electron paramagnetic resonance (EPR) measurements have been made on crystals powders of several quaternary chalcogenides the type Cu2AIIBIVX4, where AII = Zn, Mn, Fe, or Co, BIV Si, Ge, Sn, X S Se. The electrical properties these compounds are extrinsic, but their magnetic do not appear to be affected by impurities. moments Cu2MnBX4 decrease with increasing covalency MnX bond, those Cu2FeGeS4 Cu2CoGeS4 reflect an orbital contribution moment. Both Weiss constants ordering temperatures in show evolution from antiferromagnetism ferromagnetism separation between moments. Magnetic single Cu2MnGeS4, Cu2CoGeS4, indicate that only latter is anisotropic. EPR Cu2ZnGeS4 doped nominally 0.1% Mn reveal Mn2+ experiences axial distortion bond ionicity same as ZnS.
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sci-hub.se 参考文章(25)
Harald Schäfer, Chemical Transport Reactions ,(1964)
R. Nitsche, D.F. Sargent, P. Wild, Crystal growth of quaternary 122464 chalcogenides by iodine vapor transport Journal of Crystal Growth. ,vol. 1, pp. 52- 53 ,(1967) , 10.1016/0022-0248(67)90009-7
W. Schäfer, R. Nitsche, Tetrahedral quaternary chalcogenides of the type Cu2IIIVS4(Se4) Materials Research Bulletin. ,vol. 9, pp. 645- 654 ,(1974) , 10.1016/0025-5408(74)90135-4
J. L. Shay, B. Tell, H. M. Kasper, Visible Stimulated Emission in Ternary Chalcopyrite Sulfides and Selenides Applied Physics Letters. ,vol. 19, pp. 366- 368 ,(1971) , 10.1063/1.1653955
Donald M. Schleich, Aaron Wold, Optical and electrical properties of quarternary chalcogenides Materials Research Bulletin. ,vol. 12, pp. 111- 114 ,(1977) , 10.1016/0025-5408(77)90150-7
W.S Glaunsinger, EPR study of exchange interactions in EuxYb1−xB6☆ Journal of Magnetic Resonance. ,vol. 18, pp. 265- 275 ,(1975) , 10.1016/0022-2364(75)90125-0
Glen Emery HOFMANN, William Stanley GLAUNSINGER, EPR Investigation of the Mn(II) Binding Sites in Glutamine Synthetase (Escherichia coli W)I. High-Affinity Binding Sites Journal of Biochemistry. ,vol. 83, pp. 1769- 1778 ,(1978) , 10.1093/OXFORDJOURNALS.JBCHEM.A132093
B. T. Allen, Zero‐Field Splitting Parameter of the Mn++ Ion in Glassy and in Polycrystalline Media Journal of Chemical Physics. ,vol. 43, pp. 3820- 3826 ,(1965) , 10.1063/1.1696569
J. H. Van Vleck, The Dipolar Broadening of Magnetic Resonance Lines in Crystals Physical Review. ,vol. 74, pp. 1168- 1183 ,(1948) , 10.1103/PHYSREV.74.1168
D.S. Chemla, P.J. Kupecek, D.S. Robertson, R.C. Smith, Silver thiogallate, a new material with potential for infrared devices Optics Communications. ,vol. 3, pp. 29- 31 ,(1971) , 10.1016/0030-4018(71)90207-0