Treatment of fluid catalytic cracking spent catalysts to recover lanthanum and cerium: Comparison between selective precipitation and solvent extraction

作者: Valentina Innocenzi , Francesco Ferella , Ida De Michelis , Francesco Vegliò

DOI: 10.1016/J.JIEC.2014.09.014

关键词:

摘要: Abstract The paper is focused on the study of hydrometallurgical processes for recovery rare earths (RE) from fluid catalytic cracking catalysts (FCCC). According to experimental results two were proposed: in first one RE recovered as double sulfates by selective precipitation with sodium hydroxide after leaching sulfuric acid. second approach consisted dissolution powder acids, solvent extraction (2-ethylhexyl)phosphoric acid (D2EHPA), stripping and oxalates using oxalic Experiments showed that was found be beneficial terms achieving improved final products quality greater purity (∼98%).

参考文章(19)
Jong-Young Kim, Ung-Soo Kim, Myeong-Seop Byeon, Woo-Kyu Kang, Kwang-Teak Hwang, Woo-Seok Cho, Recovery of cerium from glass polishing slurry Journal of Rare Earths. ,vol. 29, pp. 1075- 1078 ,(2011) , 10.1016/S1002-0721(10)60601-1
William Todd Owens, Xingtao Gao, Process For Metal Recovery From Catalyst Waste ,(2011)
Khalifa Al-Jabri, Mahad Baawain, Ramzi Taha, Zahran Saif Al-Kamyani, Khalid Al-Shamsi, Aysser Ishtieh, Potential use of FCC spent catalyst as partial replacement of cement or sand in cement mortars Construction and Building Materials. ,vol. 39, pp. 77- 81 ,(2013) , 10.1016/J.CONBUILDMAT.2012.05.035
Pingwei Zhang, Toshiro Yokoyama, Osamu Itabashi, Yoshito Wakui, Toshishige M. Suzuki, Katsutoshi Inoue, Hydrometallurgical process for recovery of metal values from spent nickel-metal hydride secondary batteries Hydrometallurgy. ,vol. 50, pp. 61- 75 ,(1998) , 10.1016/S0304-386X(98)00046-2
Daniel Assumpção Bertuol, Andréa Moura Bernardes, Jorge Alberto Soares Tenório, Spent NiMH batteries—The role of selective precipitation in the recovery of valuable metals Journal of Power Sources. ,vol. 193, pp. 914- 923 ,(2009) , 10.1016/J.JPOWSOUR.2009.05.014
Valentina Innocenzi, Ida De Michelis, Bernd Kopacek, Francesco Vegliò, Yttrium recovery from primary and secondary sources: a review of main hydrometallurgical processes Waste Management. ,vol. 34, pp. 1237- 1250 ,(2014) , 10.1016/J.WASMAN.2014.02.010
Koen Binnemans, Peter Tom Jones, Bart Blanpain, Tom Van Gerven, Yongxiang Yang, Allan Walton, Matthias Buchert, Recycling of rare earths: a critical review Journal of Cleaner Production. ,vol. 51, pp. 1- 22 ,(2013) , 10.1016/J.JCLEPRO.2012.12.037
L Pietrelli, B Bellomo, D Fontana, M.R Montereali, Rare earths recovery from NiMH spent batteries Hydrometallurgy. ,vol. 66, pp. 135- 139 ,(2002) , 10.1016/S0304-386X(02)00107-X
Yuren Jiang, Atsushi Shibayama, Kejun Liu, Toyohisa Fujita, A hydrometallurgical process for extraction of lanthanum, yttrium and gadolinium from spent optical glass Hydrometallurgy. ,vol. 76, pp. 1- 9 ,(2005) , 10.1016/J.HYDROMET.2004.06.010