Ultra-low-density GNS/CA composite aerogels with ultra-high specific surface for dye removal

作者: Wei Sun , Ai Du , Bin Zhou , Jun Shen , Shangming Huang

DOI: 10.1007/S10971-016-4047-7

关键词:

摘要: Ultra-low-density graphene nanosheet (GNS)/carbon composite aerogels (CAs) were prepared via GO (graphene oxide)/RF (resorcinol–formaldehyde) aerogel composite, supercritical fluid drying, and carbonization. Graphene oxide was found to act as an efficient anti-shrinkage additive in the carbonization process, making linear shrinkage ratios decrease from 78 % only 10 % (25 % content). The density of thus decreases 115 24.4 mg cm−3. 25 % GO-composited exhibits over two times modulus increase 11 specific comparison with pure carbon aerogel. microstructure results show that is fully cross-linked RF polymers, makes reaction more sufficient ultimately strengthens nanostructure withstand damage resultant exhibited super high surface area (as 2899 m2 g−1), good mechanical property, adsorption capacity 403 mg g−1 for methylene blue.

参考文章(48)
T Baumann, M Worsley, J Satcher, Carbon Aerogels for Hydrogen Storage Office of Scientific and Technical Information (OSTI). ,(2008) , 10.2172/945616
Y. Hanzawa, K. Kaneko, N. Yoshizawa, R.W. Pekala, M.S. Dresselhaus, The Pore Structure Determination of Carbon Aerogels Adsorption-journal of The International Adsorption Society. ,vol. 4, pp. 187- 195 ,(1998) , 10.1023/A:1008839913594
Lorna J. Gibson, Michael F. Ashby, Cellular Solids: Structure and Properties ,(1988)
C. Hontoria-Lucas, A.J. López-Peinado, J.de D. López-González, M.L. Rojas-Cervantes, R.M. Martín-Aranda, Study of oxygen-containing groups in a series of graphite oxides: Physical and chemical characterization Carbon. ,vol. 33, pp. 1585- 1592 ,(1995) , 10.1016/0008-6223(95)00120-3
Kang Guo, Huaihe Song, Xiaohong Chen, Xian Du, Liang Zhong, Graphene oxide as an anti-shrinkage additive for resorcinol–formaldehyde composite aerogels Physical Chemistry Chemical Physics. ,vol. 16, pp. 11603- 11608 ,(2014) , 10.1039/C4CP00592A
Hyounmyung Park, Junyoung Seo, Sungwon Hwang, Young-Mok Rhym, Sung Hyeon Baeck, Sang Eun Shim, Influence of graphene nanoplatelets content on the structure and properties of macroporous carbon foams prepared by organic colloidal templates Journal of Materials Science. ,vol. 49, pp. 2063- 2069 ,(2014) , 10.1007/S10853-013-7896-2
Yu-Run Lin, Hsisheng Teng, Mesoporous carbons from waste tire char and their application in wastewater discoloration Microporous and Mesoporous Materials. ,vol. 54, pp. 167- 174 ,(2002) , 10.1016/S1387-1811(02)00380-3
Ai Du, Bin Zhou, Zhihua Zhang, Jun Shen, A Special Material or a New State of Matter: A Review and Reconsideration of the Aerogel Materials. ,vol. 6, pp. 941- 968 ,(2013) , 10.3390/MA6030941
Yanwu Zhu, Shanthi Murali, Weiwei Cai, Xuesong Li, Ji Won Suk, Jeffrey R Potts, Rodney S Ruoff, None, Graphene and Graphene Oxide: Synthesis, Properties, and Applications Advanced Materials. ,vol. 22, pp. 3906- 3924 ,(2010) , 10.1002/ADMA.201001068