Kristallin‐flüssige trans‐4‐n‐Alkylcyclohexan‐carbonsäurephenylester

作者: H.-J. Deutscher , B. Laaser , W. Dölling , H. Schubert

DOI: 10.1002/PRAC.19783200204

关键词:

摘要: Liquid Crystalline Phenyl-trans-4-n-alkylcyclohexanecarboxylates The syntheses of p-substituted phenyl-trans-4-n-alkylcyclohexanecarboxylates 1–12 and cyclohexyl-p-n-alkylbenzoates 15–17 their mesomorphic properties are described. p-n-Alkoxyphenyl-trans-4-n-alkylcyclohexanecarboxylates 1–8 exhibit larger thermal stability mesophases than analogous phenylbenzoates 13. Trans-4-subst. S-phenyl-thiocylohexanecarboxylates 19 on the other side less stable.

参考文章(8)
W. E. Bacon, Glenn H. Brown, Liquid Crystal Solvents as Reaction Media for the Claisen Rearrangement Molecular Crystals and Liquid Crystals. ,vol. 6, pp. 155- 159 ,(1969) , 10.1080/15421406908082956
Joseph A. Castellano, Joel E. Goldmacher, Lucian A. Barton, Jean S. Kane, Liquid crystals. II. Effects of terminal group substitution on the mesomorphic behavior of some benzylideneanilines Journal of Organic Chemistry. ,vol. 33, pp. 3501- 3504 ,(1968) , 10.1021/JO01273A030
Hermann Schubert, Ruth Dehne, Volkhard Uhlig, Kristallin-flüssige trans-4-n-Alkyl-cyclohexan-1-carbonsäuren Zeitschrift für Chemie. ,vol. 12, pp. 219- 220 ,(2010) , 10.1002/ZFCH.19720120604
J. P. Van Meter, B. H. Klanderman, Mesomorphic Properties of Some Phenyl Benzoate Dericatives Molecular Crystals and Liquid Crystals. ,vol. 22, pp. 271- 284 ,(1973) , 10.1080/15421407308083350
Michael J. S. Dewar, Ronald S. Goldberg, Role of p-phenylene groups in nematic liquid crystals Journal of the American Chemical Society. ,vol. 92, pp. 1582- 1586 ,(1970) , 10.1021/JA00709A026
Ernest L. Eliel, Thomas J. Brett, A Convenient Separation of cis- and trans- Methoxycyclohexanols Journal of Organic Chemistry. ,vol. 28, pp. 1923- 1924 ,(1963) , 10.1021/JO01042A520
Michael J. S. Dewar, Robert M. Riddle, Factors influencing the stabilities of nematic liquid crystals Journal of the American Chemical Society. ,vol. 97, pp. 6658- 6662 ,(1975) , 10.1021/JA00856A010
Ralf Steinsträsser, Nematische Systeme, V Zeitschrift für Naturforschung B. ,vol. 27, pp. 774- 779 ,(1972) , 10.1515/ZNB-1972-0711