Chapter 11 – Heterogeneous Catalysis on Solids

作者: Ljiljana Damjanovic , Aline Auroux

DOI: 10.1016/S1573-4374(08)80014-3

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摘要: This chapter discusses various studies in which calorimetry have been used to characterize zeolites, oxides, and metallic catalysts. It is apparent from the results literature that microcalorimetry a very powerful technique even if it does not provide direct information about molecular nature of adsorbed species. The describes way adsorption enthalpy profile probe molecule can be surface sites. Adsorption permits an accurate determination strength distribution sites based on heat suitable molecules differential versus coverage curve. A survey applications for heterogeneous catalysis are described with particular emphasis acid–base properties sieves, metal supported oxides. Additional study reducible oxides their redox character discussed chapter.

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