Fabrication and application of Diachem® electrodes

作者: M. Fryda , Th. Matthée , S. Mulcahy , A. Hampel , L. Schäfer

DOI: 10.1016/S0925-9635(03)00261-9

关键词:

摘要: Conductive diamond coated electrodes have undergone intensive investigation over the past number of years. The unique electrochemical properties such as their extreme chemical resistance, even at high doping concentrations, and overvoltage for water electrolysis opens door to numerous applications. For industrial use extremely promising electrode material sufficient availability, also large area is necessary. development DIACHEM® therefore has been performed on a range base materials geometries. production these HFCVD process used which allows reproducible coatings substrates up 50×100 cm. A with boron setting resistivity coating in 5 100 m Ω extent developed by now means that they can presently be applied various most important applications include: waste treatment, particular mineralization toxic organic compounds; disinfection water; circulation systems are only possible through an recycling process; synthesis, from strong oxidising solutions galvanic processes chrome baths. Previous investigations shown results either significant improvement effectiveness or was this material. user gains combination typical advantages efficiency which, turn, generated enormous interest In order satisfy interest, CONDIAS GmbH offers commercially.

参考文章(16)
Claus-Peter Klages, Andre Perret, Dennie Herrmann, Didier Gandini, Christos Comninellis, Lothar Schafer, Werner Haenni, Matthias Fryda, Properties of diamond electrodes for wastewater treatment New Diamond and Frontier Carbon Technology. ,vol. 9, pp. 229- 240 ,(1999)
K. Rajeshwar, J.G. Ibanez, G.M. Swain, Electrochemistry and the environment Journal of Applied Electrochemistry. ,vol. 24, pp. 1077- 1091 ,(1994) , 10.1007/BF00241305
Fritz H. Frimmel, Christian Zwiener, Georg Kleiser, Oxidationsverfahren in der Wasseraufbereitung Nachrichten Aus Der Chemie. ,vol. 48, pp. 32- 35 ,(2000) , 10.1002/NADC.20000480113
Michael C. Granger, Greg M. Swain, The influence of surface interactions on the reversibility of ferri/ferrocyanide at boron-doped diamond thin-film electrodes Journal of The Electrochemical Society. ,vol. 146, pp. 4551- 4558 ,(1999) , 10.1149/1.1392673
Yurii V Pleskov, Synthetic diamond in electrochemistry Russian Chemical Reviews. ,vol. 68, pp. 381- 392 ,(1999) , 10.1070/RC1999V068N05ABEH000494
S. Ferro, A. De Battisti, I. Duo, Ch. Comninellis, W. Haenni, A. Perret, Chlorine Evolution at Highly Boron‐Doped Diamond Electrodes Journal of The Electrochemical Society. ,vol. 147, pp. 2614- 2619 ,(2000) , 10.1149/1.1393578
Heidi B. Martin, Alberto Argoitia, Uziel Landau, Alfred B. Anderson, John C. Angus, Hydrogen and Oxygen Evolution on Boron‐Doped Diamond Electrodes Journal of The Electrochemical Society. ,vol. 143, ,(1996) , 10.1149/1.1836901
Matthias Frytda, Andreas Dietz, Thorsten Mattée, Lother Schäfer, Claus-Peter Klages, Diamantschichten für die chemische Industrie Nachrichten Aus Chemie Technik Und Laboratorium. ,vol. 45, pp. 379- 382 ,(1997) , 10.1002/NADC.19970450410
Tata N. Rao, I. Yagi, T. Miwa, D. A. Tryk, A. Fujishima, Electrochemical Oxidation of NADH at Highly Boron-Doped Diamond Electrodes Analytical Chemistry. ,vol. 71, pp. 2506- 2511 ,(1999) , 10.1021/AC981376M