Discovering Vanished Paints and Naturally Formed Gold Nanoparticles on 2800 Years Old Phoenician Ivories Using SR-FF-MicroXRF with the Color X-ray Camera

作者: Ina Reiche , Katharina Müller , Marie Albéric , Oliver Scharf , Andrea Wähning

DOI: 10.1021/AC4006167

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摘要: Phoenician ivory objects (8th century B.C., Syria) from the collections of Badisches Landesmuseum, Karlsruhe, Germany, have been studied with full field X-ray fluorescence microimaging, using synchrotron radiation (SR-FF-microXRF). The innovative Color Camera (CXC), a full-field detection device (SLcam), was used at beamline ANKA facility (ANKA-FLUO, KIT, Germany) to noninvasively study trace metal distributions surface archeological objects. outstanding strength imaging technique CXC is capability record XRF spectrum spatial resolution 48 μm on zone size 11.9 × 12.3 mm2 (264 264 pixels). For each analyzed region, 69696 spectra were simultaneously recorded. principal elements detected are P, Ca, and Sr, coming material itself; Cu, characteristic pigments; Fe Pb, representing sediments or Mn, revealing deposited soil minerals; Ti, i...

参考文章(25)
Ina Reiche, Guillaume Morin, Christian Brouder, Vicente Armando Solé, Pierre-Emmanuel Petit, Colette Vignaud, Thomas Calligaro, Michel Menu, Manganese accommodation in fossilised mastodon ivory and heat-induced colour transformation Evidence by EXAFS European Journal of Mineralogy. ,vol. 14, pp. 1069- 1073 ,(2002) , 10.1127/0935-1221/2002/0014-1069
O. Scharf, S. Ihle, I. Ordavo, V. Arkadiev, A. Bjeoumikhov, S. Bjeoumikhova, G. Buzanich, R. Gubzhokov, A. Günther, R. Hartmann, M. Kühbacher, M. Lang, N. Langhoff, A. Liebel, M. Radtke, U. Reinholz, H. Riesemeier, H. Soltau, L. Strüder, A. F. Thünemann, R. Wedell, Compact pnCCD-Based X-ray Camera with High Spatial and Energy Resolution: A Color X-ray Camera Analytical Chemistry. ,vol. 83, pp. 2532- 2538 ,(2011) , 10.1021/AC102811P
Jurate Kumpiene, Anders Lagerkvist, Christian Maurice, Stabilization of As, Cr, Cu, Pb and Zn in soil using amendments – A review Waste Management. ,vol. 28, pp. 215- 225 ,(2008) , 10.1016/J.WASMAN.2006.12.012
Joris Dik, Koen Janssens, Geert Van Der Snickt, Luuk van der Loeff, Karen Rickers, Marine Cotte, Visualization of a lost painting by Vincent van Gogh using synchrotron radiation based X-ray fluorescence elemental mapping. Analytical Chemistry. ,vol. 80, pp. 6436- 6442 ,(2008) , 10.1021/AC800965G
I. Ordavo, S. Ihle, V. Arkadiev, O. Scharf, H. Soltau, A. Bjeoumikhov, S. Bjeoumikhova, G. Buzanich, R. Gubzhokov, A. Günther, R. Hartmann, P. Holl, N. Kimmel, M. Kühbacher, M. Lang, N. Langhoff, A. Liebel, M. Radtke, U. Reinholz, H. Riesemeier, G. Schaller, F. Schopper, L. Strüder, C. Thamm, R. Wedell, A new pnCCD-based color X-ray camera for fast spatial and energy-resolved measurements Nuclear Instruments & Methods in Physics Research Section A-accelerators Spectrometers Detectors and Associated Equipment. ,vol. 654, pp. 250- 257 ,(2011) , 10.1016/J.NIMA.2011.05.080
Wolfgang Haiss, Nguyen T. K. Thanh, Jenny Aveyard, David G. Fernig, Determination of size and concentration of gold nanoparticles from UV-vis spectra Analytical Chemistry. ,vol. 79, pp. 4215- 4221 ,(2007) , 10.1021/AC0702084
X.W Su, F.Z Cui, Hierarchical structure of ivory : from nanometer to centimeter Materials Science and Engineering: C. ,vol. 7, pp. 19- 29 ,(1999) , 10.1016/S0928-4931(98)00067-8