Interactive forces at silica/organic solution interfaces
作者： J. Jednačak-Bišćan , D. Čukman
DOI: 10.1016/0166-6622(89)80044-7
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摘要: Abstract The strength and the nature of interaction hydroxylated dehydroxylated silica with chosen adsorbates was interpreted on basis heat adsorption simple organic molecules (probes) approximately same shape but significantly different dipole moments relative basicities. Flow microcalorimetry used for measurements (displacement). In all cases, highest heats silica, in range from − 10 to 30 μJ cm −2 , were found basic substances, regardless their moment. These results supported by immersion measurements, using batch calorimetry amino spin probe displacement, measured electron resonance (ESR).
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J Jednačak-Bišćan, V Pravdić, W Haller, Adsorption phenomena on glass surfaces. IV: Surface acidity of silica and glasses Journal of Colloid and Interface Science. ,vol. 121, pp. 345- 354 ,(1988) , 10.1016/0021-9797(88)90438-9
Joseph. Gorse, M. F. Burke, G. K. Vemulapalli, Isotherm studies of benzene and aniline on chemically modified silica surfaces Langmuir. ,vol. 3, pp. 179- 183 ,(1987) , 10.1021/LA00074A006
Frederick M. Fowkes, Mohamed A. Mostafa, Acid-Base Interactions in Polymer Adsorption Industrial & Engineering Chemistry Product Research and Development. ,vol. 17, pp. 3- 7 ,(1978) , 10.1021/I360065A002
Seiichi Kondo, Hirofumi Fujiwara, Takanori Ichii, Ikuo Tsuboi, Heat of immersion of thermally treated silica gel Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases. ,vol. 75, pp. 646- 651 ,(1979) , 10.1039/F19797500646
S. P. Zhdanov, L. S. Kosheleva, T. I. Titova, IR study of hydroxylated silica Langmuir. ,vol. 3, pp. 960- 967 ,(1987) , 10.1021/LA00078A014
J. Jednačak-Bišćan, V. Pravdić, Adsorption phenomena on glass surfaces. III. a microcalorimetric study of adsorption of n-butanol on heat treated surfaces of controlled pore glass Thermochimica Acta. ,vol. 53, pp. 203- 213 ,(1982) , 10.1016/0040-6031(82)85009-0
D.N Furlong, F Rouquerol, J Rouquerol, K.S.W Sing, Adsorption microcalorimetric study of rutile and silica-coated rutile Journal of Colloid and Interface Science. ,vol. 75, pp. 68- 73 ,(1980) , 10.1016/0021-9797(80)90350-1
M. L. Hair, W. Hertl, Reactivity of boria-silica surface hydroxyl groups The Journal of Physical Chemistry. ,vol. 77, pp. 1965- 1969 ,(1973) , 10.1021/J100635A008
A. J. Tyler, J. A. G. Taylor, B. A. Pethica, J. A. Hockey, Heat of immersion studies on characterized silicas Transactions of the Faraday Society. ,vol. 67, pp. 483- 492 ,(1971) , 10.1039/TF9716700483
A. V. Kiselev, The effect of the geometrical structure and the chemistry of oxide surfaces on their adsorption properties Discussions of the Faraday Society. ,vol. 52, pp. 14- 32 ,(1971) , 10.1039/DF9715200014