On the quantum theory of electron transfer: effect of potential surfaces of the reactants and products.

摘要: In this study the electron transfer theory for high frequency intramolecular mode and low medium has been rederived using different methods. For a single-mode case when reactant surface is not in thermal equilibrium but thermocoherent state authors have derived rate discussed about quantum features of rate. limit very temperatures expressions are analytically compared with distribution. Secondly, Franck-Condon factor multimode displaced, distorted, Duschinsky rotated adiabatic potential surfaces to obtain Lastly, systematic investigation made show temperature dependence on due displacement, distortion, rotation harmonic energy product manifold.