Purification of yttrium to 4N5+ purity

作者: Zhiqi Zhang , Zhiqiang Wang , Ruiying Miao , Qiong Zhu , Dehong Chen

DOI: 10.1016/J.VACUUM.2014.04.007

关键词:

摘要: Abstract Purification of yttrium by vacuum distillation was carried out and the purification process studied. More than 60 metallic impurity elements input as well purified Y were analysed using glow discharge mass spectrometry (GDMS) C, N, O, S interstitial gas analysis (IGA). The confirmed reduction total content from −4  Pa; meanwhile, decreased to low content, in which O 75 ppmw. evaporation rate mean free path calculated under experimental conditions this paper.

参考文章(15)
A. Zaiour, K. Zahraman, M. Roumie, J. Charara, A. Fawaz, F. Lmai, M. Hage-Ali, Purification of tellurium to nearly 7N purity Materials Science and Engineering B-advanced Functional Solid-state Materials. ,vol. 131, pp. 54- 61 ,(2006) , 10.1016/J.MSEB.2006.03.029
S.T. Ali, N.R. Munirathnam, C. Sudheer, R.C. Reddy, M.R.P. Reddy, T.L. Prakash, Reduction of trace oxygen by hydrogen leaking during selective vaporization to produce ultra-pure cadmium for electronic applications Materials Letters. ,vol. 61, pp. 1512- 1516 ,(2007) , 10.1016/J.MATLET.2006.07.070
Jin Hong, Sun Guoqiang, Mechanical Properties, Purifying Techniques and Processing Methods of Metal Yttrium Journal of Rare Earths. ,vol. 24, pp. 362- 366 ,(2006) , 10.1016/S1002-0721(07)60402-5
C.E. Habermann, A.H. Daane, THE PREPARATION AND PROPERTIES OF DISTILLED YTTRIUM Journal of The Less Common Metals. ,vol. 5, pp. 134- 139 ,(1963) , 10.1016/0022-5088(63)90006-7
Zhiqi Zhang, Zhiqiang Wang, Dehong Chen, Ruiying Miao, Qiong Zhu, Xiaowei Zhang, Lin Zhou, Zong-an Li, Purification of praseodymium to 4N5+ purity Vacuum. ,vol. 102, pp. 67- 71 ,(2014) , 10.1016/J.VACUUM.2013.11.008
H.J. Nolting, C.R. Simmons, J.J. Klingenberg, Preparation and properties of high purity yttrium metal Journal of Inorganic and Nuclear Chemistry. ,vol. 14, pp. 208- 216 ,(1960) , 10.1016/0022-1902(60)80260-6
A. H. Daane, F. H. Spedding, Preparation of Yttrium and Some Heavy Rare Earth Metals Journal of The Electrochemical Society. ,vol. 100, pp. 442- 444 ,(1953) , 10.1149/1.2780875
DS Prasad, NR Munirathnam, JV Rao, TL Prakash, None, Purification of tellurium up to 5N by vacuum distillation Materials Letters. ,vol. 59, pp. 2035- 2038 ,(2005) , 10.1016/J.MATLET.2005.02.012
Shaohua YANG, Fengli YANG, Chunfa LIAO, Mingzhou Li, Xu WANG, Electrodeposition of magnesium-yttrium alloys by molten salt electrolysis Journal of Rare Earths. ,vol. 28, pp. 385- 388 ,(2010) , 10.1016/S1002-0721(10)60322-5
T.H. Okabe, T.N. Deura, T. Oishi, K. Ono, D.R. Sadoway, Electrochemical deoxidation of yttrium-oxygen solid solutions Journal of Alloys and Compounds. ,vol. 237, pp. 150- 154 ,(1996) , 10.1016/0925-8388(95)02129-9