Electrospinning and characterization of medium-molecular-weight poly(vinyl alcohol)/high-molecular-weight poly(vinyl alcohol)/montmorillonite nanofibers

作者: Hyun Mi Ji , Hyun Woo Lee , Mohammad Rezaul Karim , In Woo Cheong , Eun A Bae

DOI: 10.1007/S00396-009-2019-Y

关键词:

摘要: Submicron fibers of medium-molecular-weight poly(vinyl alcohol) (MMW-PVA), high-molecular-weight (HMW-PVA), and montmorillonite clay (MMT) in aqueous solutions were prepared by electrospinning technique. The effect HMW-PVA MMT on the morphology mechanical properties MMW-PVA/HMW-PVA/MMT nanofibers investigated for first time. Scanning electron microscopy, viscometer, tensile strength testing machine, thermal gravimetric analyzer (TGA), transmission microscopy (TEM) utilized to characterize PVA/MMT properties. MMW-PVA/HMW-PVA ratios concentration played important roles nanofiber's TEM data demonstrated that exfoliated layers well distributed within nanofibers. It was also found property stability increased with contents.

参考文章(27)
E. Zussman, A. Theron, A. L. Yarin, Formation of nanofiber crossbars in electrospinning Applied Physics Letters. ,vol. 82, pp. 973- 975 ,(2003) , 10.1063/1.1544060
Jian Gong, Xiang-Dan Li, Bin Ding, Douk-Rae Lee, Hak-Yong Kim, Preparation and characterization of H4SiMo12O40/poly(vinyl alcohol) fiber mats produced by an electrospinning method Journal of Applied Polymer Science. ,vol. 89, pp. 1573- 1578 ,(2003) , 10.1002/APP.12325
Chunxue Zhang, Xiaoyan Yuan, Lili Wu, Yue Han, Jing Sheng, Study on morphology of electrospun poly(vinyl alcohol) mats European Polymer Journal. ,vol. 41, pp. 423- 432 ,(2005) , 10.1016/J.EURPOLYMJ.2004.10.027
H Fong, I Chun, D.H Reneker, Beaded nanofibers formed during electrospinning Polymer. ,vol. 40, pp. 4585- 4592 ,(1999) , 10.1016/S0032-3861(99)00068-3
Changlu Shao, Hak-Yong Kim, Jian Gong, Bin Ding, Douk-Rae Lee, Soo-Jin Park, Fiber mats of poly(vinyl alcohol)/silica composite via electrospinning Materials Letters. ,vol. 57, pp. 1579- 1584 ,(2003) , 10.1016/S0167-577X(02)01036-4
Mohammad Rezaul Karim, Jeong Hyun Yeum, In situ intercalative polymerization of conducting polypyrrole/montmorillonite nanocomposites Journal of Polymer Science Part B. ,vol. 46, pp. 2279- 2285 ,(2008) , 10.1002/POLB.21559
Jijun Zeng, Bethany Saltysiak, W.S. Johnson, David A. Schiraldi, Satish Kumar, Processing and properties of poly(methyl methacrylate)/carbon nano fiber composites Composites Part B-engineering. ,vol. 35, pp. 173- 178 ,(2004) , 10.1016/S1359-8368(03)00051-9
M Krumova, D López, R Benavente, C Mijangos, J.M Pereña, Effect of crosslinking on the mechanical and thermal properties of poly(vinyl alcohol) Polymer. ,vol. 41, pp. 9265- 9272 ,(2000) , 10.1016/S0032-3861(00)00287-1
Jeong Hyun Yeum, Jin Woo Kwak, Sung Soo Han, Sam Soo Kim, Byung Chul Ji, Seok Kyun Noh, Won Seok Lyoo, Water stability of high‐molecular‐weight (HMW) syndiotacticity‐rich poly(vinyl alcohol) (PVA)/HMW atactic PVA/iodine complex blend films Journal of Applied Polymer Science. ,vol. 94, pp. 1435- 1439 ,(2004) , 10.1002/APP.21048