Synthesis and characterization of poly(aniline-co-o-toluidine) copolymer

作者: D Kumar

DOI: 10.1016/S0379-6779(00)00270-8

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摘要: Abstract Poly(aniline-co-o-toluidine) copolymer has been synthesized by two techniques — chemical and electrochemical copolymerization of aniline with o-toluidine monomer. This is soluble in common organic solvents like N -methyl pyrrolidinone (NMP), chloroform, tetrahydrofuran (THF), dimethylformamide (DMF) dimethylsulphoxide (DMSO), etc. The conductivity found to be a range (e.g., when doped 1.0 M HCl) ranging from ca. 10 S/cm for homopolymer 0.1 o -toluidine. characterization carried out using cyclic voltametry, FTIR UV–VIS techniques.

参考文章(14)
Terje A Skotheim, None, Handbook of conducting polymers CRC Press. ,(1986)
David E. Stilwell, Su‐Moon Park, Electrochemistry of Conductive Polymers II . Electrochemical Studies on Growth Properties of Polyaniline Journal of The Electrochemical Society. ,vol. 135, pp. 2254- 2262 ,(1988) , 10.1149/1.2096248
Yong Cao, Paul Smith, Liquid-crystalline solutions of electrically conducting polyaniline Polymer. ,vol. 34, pp. 3139- 3143 ,(1993) , 10.1016/0032-3861(93)90381-J
Mario Leclerc, Jean Guay, LeˆH. Dao, Synthesis and properties of electrochromic polymers from toluidines Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. ,vol. 251, pp. 21- 29 ,(1988) , 10.1016/0022-0728(88)80381-4
D. Kumar, R.C. Sharma, Advances in conductive polymers European Polymer Journal. ,vol. 34, pp. 1053- 1060 ,(1998) , 10.1016/S0014-3057(97)00204-8
Zhao H. Wang, Anjan Ray, Alan G. MacDiarmid, Arthur J. Epstein, Electron localization and charge transport in poly(o-toluidine): A model polyaniline derivative Physical Review B. ,vol. 43, pp. 4373- 4384 ,(1991) , 10.1103/PHYSREVB.43.4373
Mario Leclerc, Jean Guay, Le H. Dao, Synthesis and characterization of poly(alkylanilines) Macromolecules. ,vol. 22, pp. 649- 653 ,(1989) , 10.1021/MA00192A024
Madathi Rethi, Surendra Ponrathnam, Chelanattu Raman Rajan, Facile synthesis of processable conductive water solubilized polyaniline Macromolecular Rapid Communications. ,vol. 19, pp. 119- 122 ,(1998) , 10.1002/(SICI)1521-3927(19980201)19:2<119::AID-MARC119>3.0.CO;2-#