Preparation and characterization of new ruthenium compounds with perovskite structure

作者: In-Seon Kim , Tetsurō Nakamura , Mitsuru Itoh , Yoshiyuki Inaguma

DOI: 10.1016/0025-5408(93)90141-Y

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摘要: Abstract New perovskite compounds Sr(Li 1 4 Ru 3 ) O , Sr(Na ( Sr 2 La )( Mg and 7 8 have been prepared. The crystal structures of these were determined by powder X-ray Rietveld analysis. structure was orthorhombic with space group Pnma . Electrical resistivity magnetic susceptibility measured for the samples nominal ruthenium valences from 4.0+ to 5.0+. In this study, structure, electrical conductivity properties new are discussed.

参考文章(20)
J.A. Alonso, E. Mzayek, I. Rasines, The distorted perovskite : A novel example of 1:3 B-cation ordering Journal of Solid State Chemistry. ,vol. 84, pp. 16- 22 ,(1990) , 10.1016/0022-4596(90)90180-6
J. M. Longo, P. M. Raccah, J. B. Goodenough, Magnetic Properties of SrRuO3 and CaRuO3 Journal of Applied Physics. ,vol. 39, pp. 1327- 1328 ,(1968) , 10.1063/1.1656282
Alan Callaghan, Carl W. Moeller, Roland Ward, Magnetic Interactions in Ternary Ruthenium Oxides Inorganic Chemistry. ,vol. 5, pp. 1572- 1576 ,(1966) , 10.1021/IC50043A023
Robert Greatrex, Norman N. Greenwood, Misri Lal, Inmaculada Fernandez, A study of the ruthenium(V) perovskites M2LnRuO6 (M = Ca, Ln = Y, La, or Eu; M = Sr, Ln = Y; M = Ba, Ln = La or Eu) by 99Ru Mössbauer spectroscopy and other techniques Journal of Solid State Chemistry. ,vol. 30, pp. 137- 148 ,(1979) , 10.1016/0022-4596(79)90095-1
J.A Alonso, E Mzayek, I Rasines, A new kind of B cations 1 : 3 ordering in cubic perovskites: The oxides Ba(M0.25Sb0.75)O3 (M = Li, Na) Materials Research Bulletin. ,vol. 22, pp. 69- 74 ,(1987) , 10.1016/0025-5408(87)90151-6
P.D. Battle, S.H. Kim, A.V. Powell, The crystal structure and electronic properties of Ba4Ru3MO12 (M = Li, Na, Mg, Zn Journal of Solid State Chemistry. ,vol. 101, pp. 161- 172 ,(1992) , 10.1016/0022-4596(92)90212-E