Ru-Induced Ferromagnetism and Metallicity in Mn(IV)-Rich Manganites Ln0.4Ca0.6MnO3

作者: B. Raveau , A. Maignan , C. Martin , R. Mahendiran , M. Hervieu

DOI: 10.1006/JSSC.2000.8722

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摘要: Abstract The doping of Mn sublattice by Ru in the Mn(IV)-rich manganites Ln 0.4 Ca 0.6 MnO 3 ( : Lanthanide; =La, Pr, Nd, Sm) induces an insulator-to-metal transition which is not obtained Cr doping. appearance metallicity and ferromagnetism these Ru-doped explained frame phase separation scenario, forming ferromagnetic (FM) clusters, extend as content increases. particular aptitude for promoting a FM metallic state discussed, on basis Ru(V) Ru(IV) oxidation states, are isoelectronic to Mn(IV) Mn(III), respectively. Magnetoresistance also evidenced discussed.

参考文章(17)
S. Mukherjee, R. Ranganathan, P. S. Anilkumar, P. A. Joy, Static and dynamic response of cluster glass in La0.5Sr0.5CoO3. Physical Review B. ,vol. 54, pp. 9267- 9274 ,(1996) , 10.1103/PHYSREVB.54.9267
A. Barnabé, A. Maignan, M. Hervieu, F. Damay, C. Martin, B. Raveau, Extension of colossal magnetoresistance properties to small A site cations by chromium doping in Ln0.5Ca0.5MnO3 manganites Applied Physics Letters. ,vol. 71, pp. 3907- 3909 ,(1997) , 10.1063/1.120540
Francis Studer, Olivier Toulemonde, Jeroen Goedkoop, Antoine Barnabe, Bernard Raveau, Magnetic Moments in (Cr and Ni) Doped CMR Manganites as Seen by Soft X-ray Magnetic Circular Dichroism Japanese Journal of Applied Physics. ,vol. 38, pp. 377- ,(1999) , 10.7567/JJAPS.38S1.377
P. Khalifah, R. W. Erwin, J. W. Lynn, Q. Huang, B. Batlogg, R. J. Cava, Magnetic and electronic characterization of quasi-one-dimensional La3RuO7 Physical Review B. ,vol. 60, pp. 9573- 9578 ,(1999) , 10.1103/PHYSREVB.60.9573
T. Kimura, Y. Tomioka, R. Kumai, Y. Okimoto, Y. Tokura, Diffuse Phase Transition and Phase Separation in Cr-Doped Nd 1/2 Ca 1/2 MnO 3 : A Relaxor Ferromagnet Physical Review Letters. ,vol. 83, pp. 3940- 3943 ,(1999) , 10.1103/PHYSREVLETT.83.3940
P.D. Battle, T.C. Gibb, C.W. Jones, F. Studer, Spin-glass behavior in Sr2FeRuO6 and BaLaNiRuO6: A comparison with antiferromagnetic BaLaZnRuO6 Journal of Solid State Chemistry. ,vol. 78, pp. 281- 293 ,(1989) , 10.1016/0022-4596(89)90109-6
A. Barnabé, A. Maignan, M. Hervieu, B. Raveau, Mn-site doping induced CMR properties in calcium rich manganites Pr1-xCaxMnO3(0.6 ≤ x ≤ 0.7) European Physical Journal B. ,vol. 1, pp. 145- 150 ,(1998) , 10.1007/S100510050164
In-Seon Kim, Tetsurō Nakamura, Mitsuru Itoh, Yoshiyuki Inaguma, Preparation and characterization of new ruthenium compounds with perovskite structure Materials Research Bulletin. ,vol. 28, pp. 1029- 1039 ,(1993) , 10.1016/0025-5408(93)90141-Y
P.D. Battle, C.W. Jones, F. Studer, The crystal and magnetic structures of Ca2NdRuO6, Ca2HoRuO6, and Sr2ErRuO6 Journal of Solid State Chemistry. ,vol. 90, pp. 302- 312 ,(1991) , 10.1016/0022-4596(91)90147-A
P.D. Battle, C.W. Jones, The crystal and magnetic structures of Sr2LuRuO6, Ba2YRuO6, and Ba2LuRuO6 Journal of Solid State Chemistry. ,vol. 78, pp. 108- 116 ,(1989) , 10.1016/0022-4596(89)90133-3