Organometallic Chemistry of Arene Ruthenium and Osmium Complexes

摘要: Publisher Summary This chapter focuses on the organometallic chemistry and new aspects of arene ruthenium osmium complexes. It explores that complexes play an increasingly important role in chemistry. They appear to be good starting materials for access reactive metal hydrides or 16-electron (0) intermediates have been used recently carbon-hydrogen bond activation. Various methods cyclopentadienyl, borane, carborane reported. Recently, from classic has grown area making significant contributions cyclophanes. These compounds are potential precursors polymers, which show interesting electrical properties conductivity. The possibility coordination a two-electron ligand, addition arene, atom provides route mixed cluster compounds. Cocondensation with vapors allowed types clusters. reviews useful specific catalyst precursors, apart hydrogenation, carbon–hydrogen activation alkynes; such may become valuable reagents organic syntheses.