Basische metalle : XX. Synthese und reaktivität von C6Me6Ru(CO)PMe3. Ein stabiler aromaten-ruthenium(0)-carbonyl-komplex
作者： H. Werner , R. Werner
DOI: 10.1016/S0022-328X(00)85607-7
关键词:
摘要: Abstract Treatment of [C 6 Me RuCl 2 ] with carbon monoxide gives C Ru(CO)Cl (II) which reacts PMe 3 in the presence NH 4 PF to form Ru(CO)(PMe )Cl]PF (III). Reduction cation III NaC 10 H 8 THF yields Ru(CO)PMe (IV) is first stable mononuclear areneruthenium(0) carbonyl complex. IV CF COOH/NH and MeI/NH give salts RuH(CO)PMe ]PF (V) RuCH (CO)PMe (VI).
elsevier.com
sci-hub.se 参考文章(3)
A. Spencer, H. Werner, Basic metals XVI. Interconversion of alkyl- and acyl-cobalt(III) complexes derived from cyclopentadienylcarbonyl(trimethylphosphine)cobalt(I) Journal of Organometallic Chemistry. ,vol. 171, pp. 219- 228 ,(1979) , 10.1016/S0022-328X(00)81543-0
Helmut Werner, Rainer Werner, Ein neuer Typ von Ruthenium(0)-Komplexen mit Halbsandwichstruktur: C6H6RuL2[1] Angewandte Chemie. ,vol. 90, pp. 721- 722 ,(1978) , 10.1002/ANGE.19780900916
Helmut Werner, Rainer Werner, A New Type of Ruthenium(0) Complex with a Half‐Sandwich Structure: C6H6RuL2 Angewandte Chemie. ,vol. 17, pp. 683- 684 ,(1978) , 10.1002/ANIE.197806831